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Is the water in a crystalline sugar solution endothermic or exothermic?

2020-04-16 View Original

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Is the water in a crystalline sugar solution endothermic or exothermic? Ask for the source
Reply #2 2020-04-16
It should usually be endothermic, because crystallization from a solution is a process of entropy reduction that requires energy input from outside the system. Additionally, solvent evaporation causes the solute to precipitate, and this process itself also requires heat absorption.
Reply #3 2020-04-16
Thank you very much. However, after checking some information, I found that heat is released, and quite a lot of it at that. I also conducted a simple dissolution experiment on my own, but there was no significant change in temperature
Reply #4 2020-04-16
If a pure substance solidifies or crystallizes from a liquid state, it is definitely exothermic, due to the phase transition heat. However, in the case of a solution, when the solute precipitates out of the system and the proportion of solvent is reduced through solvent evaporation, heat should be absorbed. If the solubility of a solute decreases due to cooling, it is necessary to conduct a detailed analysis of the thermodynamic changes in such a situation.

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