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What about the statement in the second volume of Physical Chemistry published by Nanjing University, which claims that the maximum one-way conversion rate for ammonia synthesis is 26%?

2022-10-28View Original

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This post was last edited by wenyuyu on 2022-10-28 at 18:50. Hello, everyone: There is a question in the second volume of Physical Chemistry published by Nanjing University regarding the maximum one-way conversion rate for ammonia synthesis being 26% In the fifth edition of Physical Chemistry, Volume 2, published by Nanjing University, page 154 in Chapter 11: Fundamentals of Chemical Kinetics (II), it is stated as follows: “Under conditions of 30 Mpa and 773 K, the maximum possible conversion rate for ammonia synthesis, based on thermodynamic analysis, is 26%.” How is this 26% calculated? Are there any who are engaged in chemical reaction research? How should this question be answered? Thank you, experts, for your guidance!
Reply #22022-10-31
Under these operating conditions, a reaction equilibrium should exist; check the literature. Check whether Gibbs is zero
Reply #32022-10-31
Because within the reactor, the products cannot be removed, which means that the reaction at these temperature and pressure conditions has reached equilibrium.

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