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Alkylation corrosion problem

2024-01-06View Original

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In the Rums process, hydrogen was detected in the non-condensable gases from the refrigerant tanks; the total sulfur content was 2000+. The hydrogen level decreases after those non-condensable gases are discharged, but it rises again later on. Logically, hydrogen shouldn’t be present after acid washing and passivation. Have other professionals encountered this issue? ? Is there any corrosion?
Reply #22024-01-06
In the Rums process, if hydrogen is detected in the gases from the condenser, it indicates that there may be corrosion issues within the system. Sulfide corrosion can lead to the release of hydrogen. Although pickling and passivation can reduce corrosion, it can still occur if there are impurities in the raw materials or products, abnormal operating conditions, or equipment defects. This may be why hydrogen is still detected after pickling and passivation. It is recommended to check the sulfur content of the raw materials, as well as for any issues such as equipment leaks, dead zones, or inappropriate material selection within the system. The actual situation may require specific analysis, and it is also recommended to consult professional experts in chemical corrosion for a detailed examination and analysis. .
Reply #32024-04-10
I’ve never done it before, but I learned by following along*.

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