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Corrosion protection in dechlorination process

2007-12-11View Original

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This post was last edited by sunjl1981 on 2013-1-6 at 23:55. The pipes in the company’s dechlorination process are suffering from severe corrosion, and I would like to know what causes this. Is it related to the amount of alkali added and the amount of sodium sulfite? # , , &
Reply #22007-12-11
Complex medium: contains brine, hypochlorites, chlorates, as well as acids and bases, along with high temperatures. The key is to select good materials, and then ensure stable operation.
Reply #32007-12-11
If ordinary carbon steel is used, the main issue is an excessive amount of sodium sulfite being added. Since sodium sulfite is a common deoxidizing agent that can effectively remove rust, it is often used for deoxidizing boilers. Meanwhile, the presence of sodium chloride in the system can lead to oxygen-induced corrosion, especially at the interfaces in contact with air. The rust resulting from this oxygen-induced corrosion is quickly removed by sodium sulfite, exposing a new surface; this new surface is then rapidly oxidized again, and this cycle repeats itself, resulting in severe corrosion of the system’s pipes
Reply #42007-12-15
Question for Floor 3: The presence of sodium chloride in the system can cause oxygen-induced corrosion. What does that mean? Has electrochemical corrosion occurred? Could you be more specific? Is there any way to deal with this?
Reply #52007-12-16
The medium conditions in the dechlorination process are complex and highly corrosive; when selecting materials, the following aspects should be taken into account: Dechlorination tower, jet pump (chlorine water circulation pump), dechlorination brackish water pump: titanium; CPVC is a better choice for pipes carrying dechlorinated brine, chlorine water, and high-purity hydrochloric acid ; Stainless steel for sodium sulfite pipelines and caustic soda pipelines ; The chlorine water circulation tank is lined with natural rubber; corrosion protection must be adequate, and electric spark testing must pass, as there is a possibility of hydrogen generation ; Gas exhaust fan pipeline: UPVC ;

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