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Reverse osmosis (RO) treatment device

2008-01-13View Original

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Scope of use Seawater, brackish water desalination; Medium and high pressure boiler feed water ; Food and beverage pure water ; Bottled pure water pipe quality-separated water supply, etc. Cleaning standards for membrane fouling 1.1 Under normal pressure, the product water flow rate drops to 85 to 90% of the normal value ; 1.2 In order to maintain normal product water flow, the feed water pressure after temperature correction is increased by 10 to 15% compared with normal operation. ; 1.3 The product water quality is reduced by 10-15%, and the salt permeability is increased by 10-15%. ; 1.4 The pressure difference between each RO section increases significantly. Common pollutants and cleaning methods 2.1 Calcium carbonate scale:   When the antiscalant addition system fails or when the acid addition system fails, the pH value of the water increases, then calcium carbonate may precipitate. The occurrence of calcium carbonate scale deposition should be discovered as early as possible to prevent the grown crystals from operating on the membrane surface. If calcium carbonate scale is discovered early, it can be removed by lowering the feed water pH to between 3-5 and running for 1-2 hours.   For calcium carbonate scale that has a longer precipitation time, 2% citric acid cleaning solution (control pH not less than 4) should be used for cleaning. Note: You should ensure that the pH of any cleaning solution is not lower than 4, otherwise it may cause damage to the RO membrane element. You should pay more attention especially when the temperature is high. The highest pH value should not be greater than 10. You can use sulfuric acid or hydrochloric acid to reduce the pH value, and use sodium hydroxide to increase the pH value. 2.2 Calcium sulfate scale :   Cleaning solution 2 (see Table 2) is the best way to remove calcium sulfate scale from the reverse osmosis membrane surface. 2.3 Metal oxide scale:   Deposited hydroxides (such as ferric hydroxide) can be easily removed using the calcium carbonate scale removal method described above. 2.4 Silicon scale:   For silicon scales that are not symbiotic with metal oxides or organic matter, they can generally be removed only through specialized cleaning methods. Please contact our company for detailed methods. 2.5 Accumulated sediments:   Organic sediments (such as microbial slime or mildew) can be removed with cleaning fluid. In order to prevent regeneration and reproduction, the company's approved sterilizing fluid can be used to circulate and soak in the system. Generally, it takes a longer period of soaking to be effective. If the reverse osmosis device is out of service for more than three days, it is best to use detoxification treatment. 2.6 Selection of cleaning fluid:   When cleaning reverse osmosis membrane elements, it is recommended to use the cleaning fluid listed in Table 2. It is very important to conduct chemical analysis of contaminants before determining the cleaning solution. Detailed analysis and comparison of the analysis results can ensure the selection of the best cleaning agent and cleaning method. The cleaning method and the cleaning effect obtained during each cleaning should be recorded to provide a basis for finding the best cleaning method under specific water supply conditions. It is recommended to use 1# cleaning fluid for inorganic pollutants, and 2# cleaning fluid for calcium sulfonyl and organic pollutants. It is recommended to use 3# cleaning fluid to severely punish organic contamination. All cleaning solutions can be cleaned at a temperature of 40°C for 60 minutes. The required amount of supplies is based on the amount added per 379 liters. When preparing the cleaning solution, add chemicals and cleaning water (reverse osmosis fresh water) in proportion and mix evenly. During the reverse osmosis membrane cleaning process, the cleaning solution is circulated on the high-pressure side of the membrane at low pressure and large flow rate. At this time, the membrane element is still installed in the pressure vessel, and a special cleaning device is required to complete the work.   General steps of cleaning process: 3.1 Use a pump to pump clean, free chlorine-free reverse osmosis fresh water into the pressure vessel and allow it to drain for a few minutes. 3.2 Use reverse osmosis fresh water to prepare cleaning fluid (see Table 2 for details). 3.3 Circulate the cleaning fluid in the pressure vessel for 1 hour or a preset time. For an 8-inch pressure vessel, the flow rate is 35 to 40 gallons/min (8 to 9m3/H). 3.4 After the chemical washing is completed, drain the remaining liquid in the medicine box, clean it, and then put in reverse osmosis fresh water. 3.5 Use a pump to pump the fresh water in the medicine tank into the pressure vessel and let it drain for a few minutes. 3.6 After flushing the reverse osmosis system, open the freshwater outlet discharge valve of the reverse osmosis system and put the reverse osmosis system into normal operation. After 15-30 minutes, check the quality of the freshwater discharge water (no foam, no cleaning agent, and the conductivity meets the standard). 3.7 Open the fresh water outlet valve of the reverse osmosis system, close the fresh water outlet discharge valve, and resume normal operation. Table 1 Characteristics of reverse osmosis membrane pollution and treatment methods. General characteristics of pollutants. Treatment method 1. Calcium sediments (calcium carbonate and calcium phosphate, generally occur in the second section of the system). The desalination rate drops significantly. The system pressure drop increases. The system water production decreases slightly. Clean the system with solution 1. 2. Oxides (iron, nickel, copper, etc.) The desalination rate is slightly reduced. The system pressure drop is significantly increased. The system water production is significantly reduced. Use solution 1 to clean system 3. Various colloids (iron, organic matter and silica colloids). The desalination rate is slightly reduced. The system pressure drop gradually increases. The system water production volume is gradually reduced. Use solution 2 to clean system 4. Calcium sulfate (generally occurs in the second section of the system) The desalination rate has significantly decreased. The system pressure drop has or moderately increased. The system water production has slightly decreased. Use solution 2 to clean the system 5. Organic matter sedimentation and accumulation. The desalination rate may reduce the system pressure drop and gradually increase. The system water production has slightly decreased. Use solution 2 to clean the system. When the pollution is serious, use solution 3 to clean the system. 6. Bacterial contamination. The desalination rate may decrease. The system pressure drop has increased significantly. The system water production has significantly decreased. According to the possible pollution types, choose one of the three solutions to clean the system. Instructions: The cause of pollution must be confirmed and the source of pollution must be eliminated. If you need help, please contact our company. Table 2 Recommended common cleaning methods. Ingredients of cleaning solution to prepare 100 gallons (379 liters). Amount to be added when preparing the solution. pH adjustment 1. Citric acid 2%. Reverse osmosis product water (no free chlorine) 17.0 pounds (7.7 kg). 100 gallons (379 liters). Use sodium hydroxide to adjust the pH to 4.02. Sodium tripolyphosphate EDTA tetrasodium salt reverse osmosis product water (no free chlorine) 17.0 pounds (7.7 kg). 7 pounds (3.18 kg) 100 gallons (379 liters) Adjusted to pH 10.03 with sulfuric acid Sodium tripolyphosphate Sodium dodecyl benzene sulfonate reverse osmosis product water (no free chlorine) 17.0 pounds (7.7 kg) 2.13 pounds (0.97 kg) 100 gallons (379 liters) Adjusted to pH 10.0 with sulfuric acid
Reply #22008-01-13
Reverse osmosis technology Reverse osmosis (RO) technology is a membrane separation technology developed in the 1960s. It relies on a reverse osmosis membrane to separate solvent and solute in a solution under pressure. Osmosis is a physical phenomenon. When two waters containing different concentrations of salt are separated by a semi-permeable membrane, it will be found that the water on the side with less salt content will penetrate through the membrane into the water with high salt content, but the salt contained will not penetrate until the salt concentration on both sides is melted to equalize. If a pressure is applied to the water side with high salt content, the result can also stop the above-mentioned osmosis. The pressure at this time is called osmotic pressure. If the applied pressure is increased, the water can be moved from the side with high salt content to the side with low salt content, and the salt is trapped. Therefore, applying a pressure greater than the natural osmotic pressure in the water containing salt causes the osmosis to proceed in the opposite direction, forcing the water molecules in the raw water to the other side of the membrane to obtain pure water that removes salt, microorganisms, organic matter and other substances. This is the principle of reverse osmosis. The principle diagram is as follows: http://www.china-qianqiu.com/UserFiles/Image/fan/image005.gif Characteristics of reverse osmosis technology: Reverse osmosis (RO) technology is a highly efficient and energy-saving technology. It relies on pressure to separate water and ions to achieve purification and concentration. This process has no phase change, generally does not require heating, has low energy consumption, low operating costs, no pollution, easy and reliable operation, and high water quality, making it the most energy-saving technology for seawater and brackish water desalination. It has been widely used in medicine, electronics, chemical industry, food, seawater desalination and many other industries. Reverse osmosis technology has become the preferred water treatment technology in modern industry. Reverse osmosis (RO) technology has become an important part of membrane separation technology. The use of reverse osmosis technology: (1) Desalination of brackish water and sea water ; (2) Remove organic matter, bacteria, colloids and other impurities dissolved in water ; (3) Wastewater treatment and reuse ; (4) As a concentration method, valuable components dissolved in the solution can be recovered. Reverse osmosis technology is suitable for application industries: (1) Electric power industry: boiler feed water ; (2) Electronic industry: Semiconductor industry ultrapure water, integrated circuit cleaning water ; (3) Food industry: Formula water, production water ; (4) Beverage industry: Formula water, production water, washing water ; (5) Pharmaceutical industry: Process water, preparation water, washing water, water for injection, drug concentration and separation ; (6) Chemical industry: Process water, wastewater treatment, concentration and separation of valuable substances ; (7) Drinking water project: Pure water preparation, drinking water purification ; (8) Petrochemical industry: Oilfield injection water and petrochemical wastewater advanced treatment ; (9) Seawater desalination: Production and domestic water in island areas, coastal water-scarce areas, ships, seawater oil fields, etc.

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