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Seeking help with a question regarding units

2008-02-25View Original

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In some sources, I’ve seen that the oxygen content is expressed in %mol. What does this mean? Also, is there any conversion factor between %mol and ppm wt (ppm vol)? Those who know it, please share. Thank you first
Reply #22008-02-25
It’s the mole fraction, right? Irregular way of expression. The definitions and ways of expressing the mass fraction, concentration, mass concentration, etc., of chemical substances are as follows: The mass ratio between chemical substances A and B should be expressed as: m(A)∶m(B)=2∶1 [A∶B=2∶1 is incorrect] ; The volume ratio between the chemical substances should be expressed as: V (A)∶V(B)=2∶1 ; The ratio of amounts (or molar ratio, particle count ratio) between chemical substances should be expressed as: n(A)∶n(B)=2∶1 ; A and B in parentheses should be the names or molecular formulas of the chemical substances. The mass fraction of chemical substance A should be expressed as: w(A) = 20% [A = 20% is incorrect] ; The volume fraction of the chemical substance should be expressed as: φ (A)=20% ; The molar fraction of the chemical substance should be expressed as: x (A)=20%. It should be emphasized that only the molar concentration can be referred to simply as concentration; its unit is mol/L. This can be expressed as: c(A) = 3 mol/L, or c_A = 3 mol/L. The mass concentration can be expressed as: ρ (A)=3g/L, but the mass concentration should not be abbreviated as “concentration”. It is incorrect to refer to the mass fraction, volume fraction, or molar fraction of a substance as “concentration”. The symbols m, V, n, w, φ, x, c, ρ must be used in conjunction with the molecular formula or name of a chemical substance; they cannot be used on their own. For example, expressions such as w=20%, A∶B=2∶1, or using “%” to indicate concentration are all incorrect.
Reply #32008-02-25
%mol is molar percentage; ppm wt is parts per million (by weight); ppm vol is parts per million (by volume)

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