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Issues regarding the potassium-alkali decarbonization system for synthetic ammonia phenylphthalein process

2008-03-05View Original

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I’m a beginner and have only been working with synthetic ammonia for a short time. However, from the Internet as well as from my classmates and colleagues, I’ve learned that there are quite a number of synthetic ammonia systems that use phenol-thermal potassium-alkali decarburization, but many of these systems encounter problems. Small impacts cause slight fluctuations in the system, while larger impacts require stopping the operation to replace the solution. . . . . . Decarbonization has become the bottleneck determining the quality of the entire system! ! ! ! I searched on the forum, but couldn’t find any discussions about it, so I’m raising the question again. I hope experts can give me some guidance. How to solve it and stabilize the system? ? ? ? ? ? For example: The system solution tends to form foam easily, and a large amount of defoamer is required – how can this be improved? (Does using too much defoamer have a significant impact on the system?) ; With the use of system activators, do ordinary activators change within the system, forming other substances that could affect the system? ; Experience in the control and removal of chloride ions and iron ions in the system. . System thermal load control: what level is appropriate? What are the hazards if it’s too high or too low? There are so many questions; I can’t list them all. I hope those who are more experienced will share their knowledge~~~~~~~
Reply #22008-12-08
The system solution tends to foam because it is too dirty; it is necessary to improve the management of the solution, enhance mechanical filtration, and employ activated carbon filtration when needed. Strengthen the management of chemicals when preparing potassium carbonate solutions. Too much defoamer should not be added. With the use of system activators, do ordinary activators change within the system? The control of chloride and iron ions in the system is generally maintained at 10PPM. Management of the preceding processes also needs to be strengthened. Strictly control the total vanadium content in the system. Control the thermal balance of decarburization. The production load of the system generally does not affect the stability of the decarburization system.

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