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Seek all information on diethanolamine

2008-11-18View Original

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Urgently need all information on diethanolamine; anyone who has it, please share
Reply #22009-02-02
Diethanolamine Product Code: LJ-036 Product Specifications; 99.9% Origin of the product: Dow in the United States (13,500 yuan/ton). Packaging of the product: 200 kg/barrel. Description of properties: See “Ethanolamine”. Its main physical properties are as follows: melting point 28.0°C, boiling point 269.1°C, 217°C (20 kPa), 154–155°C (1.33 kPa), 20°C (1.33 Pa); relative density 1.0828 (20/20°C); dynamic viscosity (40°C) 196.4 mPa·s; refractive index 1.4476; flash point 146°C. Soluble in water, methanol, propanone ; At 25°C, its solubility in benzene is 4.2%, in ether it is 0.8%, and in carbon tetrachloride it is less than 0.1%. It is a colorless to slightly yellowish viscous liquid when melted. It has an ammonia-like odor and is hygroscopic. It is alkaline. Its 0.1N aqueous solution has a pH of 11.0, and it can absorb carbon dioxide and hydrogen sulfide from the air. Production method: Diethanolamine is obtained by the reaction of ethylene oxide with ammonia; ethanolamine and triethanolamine are also produced as by-products. Ethylene oxide and ammonia are fed into the reactor, where a condensation reaction takes place at a reaction temperature of 30–40°C and a reaction pressure of 70.9–304 kPa to produce a mixture of mono-, di-, and triethanolamine. After dehydration and concentration at 90–120°C, this mixture is sent to three vacuum distillation columns for vacuum distillation; fractions with different boiling points are separated, thereby yielding monoethanolamine, diethanolamine, and triethanolamine products with a purity of 99%. During the reaction process, increasing the proportion of ethylene oxide leads to an increased yield of diethanolamine and triethanolamine, thereby improving their overall yield. Uses: Diethanolamine is primarily used as an absorbent for acidic gases such as CO2, H2S, and SO2, as a non-ionic surfactant, emulsifier, polishing agent, industrial gas purifier, and lubricant. It is used as a thickening agent and foam improver in shampoos and mild detergents, and as a softener in the production of synthetic fibers and leather. Diethanolamine reacts with 70% sulfuric acid to undergo dehydration and cyclization to form morpholine (i.e., 1,4-oxazacyclohexane). Both morpholine and diethanolamine are intermediates in organic synthesis; for example, they can be used to produce certain optical bleaching agents in the textile industry. The fatty acid salts of morpholine can be used as preservatives, and morpholine can also be used to manufacture the central nervous system depressant pholcodine or as a solvent. Diethanolamine is used in analytical chemistry as a reagent and as a stationary phase in gas chromatography, enabling the selective retention and separation of alcohols, diols, amines, pyridines, quinolines, piperazines, thioalcohols, thioethers, and water. Our company is a foreign-funded enterprise that places integrity at its core; it specializes in organic chemicals as well as various chemical raw materials. \"Quality helps us gain a foothold in the market, while reputation earns us customer trust.\" We maintain close partnerships with well-known international chemical companies and act as agents for their products, which are sold throughout the country and enjoy widespread support from customers. The company strictly adheres to the ISO9001:2002 international standard, and consistently upholds a market-oriented approach with quality as the top priority, customers first, and excellent service! We warmly welcome business partners from home and abroad to come and discuss matters related to business, cooperation, and investment, so as to jointly create a bright future. We handle shipping on behalf of customers from other areas; local customers can place orders by phone, and goods will be delivered to their doorsteps. We offer comprehensive and high-quality services. We warmly welcome business partners from home and abroad to come and discuss potential collaborations!
Reply #32009-02-02
Desulfurization agents such as amine solutions, MDEA, and dry gas for removing hydrogen sulfide
Reply #42009-10-09
Technical Data Sheet (MSDS) for Diethanolamine – Part 1: Chemical Name. Chinese name of the chemical: Diethanolamine; English name: diethanolamine. Other names in Chinese: ; Other names in English: . Technical data sheet identifier: Molecular formula: C4H11NO2; Molecular weight: 105.14. Part 2: Information on components/constitution. Main component: Pure substance. CAS No.: 111-42-2. Part 3: Hazard overview. Hazard category: Route of exposure: Health hazards: Inhaling the vapors or mist of this substance can irritate the respiratory tract. Inhalation of high concentrations causes coughing, headache, nausea, vomiting, and coma. Steam is highly irritating to the eyes ; Liquids or mists can cause severe eye damage, even leading to blindness. Prolonged skin contact can cause burns. High oral doses cause nausea, vomiting, and abdominal pain. Chronic effects: Prolonged and repeated exposure may cause liver and kidney damage. Environmental hazards: Flammability and explosion risk: Section 4: First aid measures. Skin contact: Immediately remove contaminated clothing and rinse with plenty of flowing water for at least 15 minutes. Seek medical attention. Eye contact: Immediately lift the eyelids and rinse thoroughly with plenty of flowing water or saline for at least 15 minutes. Seek medical attention. Inhalation: Quickly move to a place with fresh air. Keep the airways clear. If there is difficulty breathing, administer oxygen. If breathing stops, perform artificial respiration immediately. Seek medical attention. Ingestion: Rinse the mouth with water and give milk or egg white to drink. Seek medical attention. Part 5: Fire-fighting measures. Hazardous characteristics: Flammable in the presence of open flames or high temperatures. Upon heating, it decomposes to release toxic nitrogen oxide fumes. A chemical reaction can occur upon contact with strong oxidizers. It can corrode copper and its compounds. Harmful combustion products: Extinguishing method: Spray water to keep the containers at the fire site cool until the fire is extinguished. Extinguishing agents: water, dry powder, carbon dioxide, alcohol-resistant foam. Precautions and measures for fire fighting: Section 6: Emergency response to leaks. Emergency handling: Quickly evacuate people from the area contaminated by the leak to a safe zone, and isolate it while strictly restricting access. Cut off the source of fire. It is recommended that emergency responders wear self-contained positive-pressure breathing apparatus and protective suits. Do not come into direct contact with the spill. If it is a liquid. Seal the source of leakage as much as possible. Prevent entry into confined spaces such as sewers and drainage ditches. Minor leaks: Absorb with sand, vermiculite, or other inert materials. It can also be rinsed with a large amount of water, and the diluted wash water is then discharged into the wastewater system. Large-scale leakage: Build dikes or dig pits to contain it. Cover with foam to reduce vapor hazards. Transfer to a tank truck or specialized collector using a pump, and recycle it or transport it to a waste disposal facility for disposal. If it is a solid, collect it with a clean shovel and place it in a dry, clean, covered container. In the event of a large-scale leak, collect it for recycling or transport it to a waste disposal facility for disposal. Part 7: Handling, Disposal, and Storage. Handling precautions: Storage precautions: Store in a cool, well-ventilated warehouse. Keep away from flames and heat sources. The package is sealed. It should be stored separately from oxidizers, acids, etc.; mixed storage is strictly prohibited. Equip with appropriate types and quantities of fire-fighting equipment. The storage area should be equipped with emergency response equipment for leaks and appropriate containment materials. Part 8: Exposure Control/Personal Protection Maximum Allowable Concentration: China MAC: No standard established ; Former Soviet Union MAC:5 Monitoring method: Engineering controls: Operate in a closed environment and ensure proper ventilation. Provide safety showers and eye wash stations. Respiratory protection: When the dust concentration in the air exceeds the permissible level, a hooded electric-powered air-supplied filtering respirator should be worn. ; When there may be exposure to its vapors, it is recommended to wear a direct-type gas mask (half-mask). Eye protection: Protection is provided under respiratory protection. Physical protection: Wear polyethylene protective clothing. Hand protection: Wear chemical-resistant gloves. Other protections: Smoking, eating, and drinking are prohibited at the work site. After finishing work, take a shower and change. Conduct pre-employment and regular health checks. Part 9: Physicochemical Properties – Appearance and Characteristics: Colorless viscous liquid or crystals. PH: Melting point (°C): 28 Boiling point (°C): 269 (decomposition) Relative density (water=1): 1.09 Relative vapor density (air=1): 3.65 Saturated vapor pressure (kPa): 0.67 (138°C) Heat of combustion (kJ/mol): No data Critical temperature (°C): No data Critical pressure (MPa): No data Logarithm of octanol/water partition coefficient: No data Flash point (°C): 137 Ignition temperature (°C): 662 Upper explosive limit (% V/V): No data Lower explosive limit (% V/V): 1.6 Solubility: Soluble in water and ethanol; insoluble in ether and benzene. Primary uses: as an analytical reagent, an absorbent for acidic gases, a softener and lubricant, as well as in organic synthesis. Other physical and chemical properties: Part 10: Stability and Reactivity Stability: Conditions to be avoided: Incompatible substances: Acids, strong oxidizing agents, copper, zinc. Polymerization hazards: Decomposition products: Part 11: Toxicological data Acute toxicity: LD50: 1820 mg/kg (oral, rats) ; 1220 mg/kg (dermal administration in rabbits); LC50: data not available. Subacute and chronic toxicity: Irritation: Sensitization: Mutagenicity: Teratogenicity: Carcinogenicity: Other: Part XII: Ecological information. Ecotoxicity: Biodegradability: Non-biodegradability: Bioaccumulation: Other harmful effects: Part XIII: Disposal. Properties of waste: Methods of waste disposal: Relevant ** and local regulations should be consulted prior to disposal. Incineration is recommended as a disposal method. The nitrogen oxides emitted from the incinerator are removed through a scrubber. Disposal precautions: Part XIV: Transport information. Hazardous goods code: 82507. UN number: No information available. Packaging mark: Packaging category: O53. Packaging method: Steel drum with small opening ; Ordinary wooden box outside threaded-mouth glass bottles, iron-cap pressed-mouth glass bottles, plastic bottles, or metal drums/tanks ; Glass bottles with threaded mouths, plastic bottles, or tin-plated thin steel sheet drums/tanks, enclosed in floor-grid boxes, fiberboard boxes, or plywood boxes ; Corrugated cardboard box outside a tin-plated thin steel sheet barrel (tank), metal barrel (tank), plastic bottle, or metal hose. Transportation precautions: Part XV: Regulatory information. Domestic regulations on chemical safety management: Regulations on the Safety Management of Chemical Hazardous Materials (issued by the State Council on February 17, 1987), Detailed Rules for the Implementation of the Regulations on the Safety Management of Chemical Hazardous Materials (Document No. Hualao Fa 677), Provisions on the Safe Use of Chemicals in the Workplace (Document No. Laobu Fa 423), and other regulations that set out rules regarding the safe use, production, storage, transportation, and handling of chemical hazardous materials ; The Classification and Labelling of Commonly Used Hazardous Chemicals (GB 13690-92) classifies this substance as a basic corrosive of Category 8.2.

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