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Phase state after pressure reduction of the medium

2009-02-17View Original

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A mixture of crude oil along with a small amount of hydrogen and hydrogen sulfide is depressurized using a pressure reducing valve; does the temperature of the medium change before and after depressurization? Set during an adiabatic process.
Reply #22009-03-15
In my opinion, if there is a change in phase before and after pressure reduction, such as from a liquid phase to a gas phase, then the temperature must decrease. If the phase remains unchanged, the temperature change should be small
Reply #32009-03-16
It depends on how much your stress is reduced; if that leads to a change in phase, the temperature will change significantly
Reply #42009-03-16
I didn’t study physical chemistry well enough. Take a good look at the chapter on the Second Law of Thermodynamics. Generally, when pressure is reduced and volume expands, it is an endothermic process; the temperature usually decreases, and the enthalpy value is positive. If a phase change occurs, then the enthalpy of phase change must be taken into account. Regarding what the original poster mentioned – that crude oil contains very few gaseous impurities – pressure drop has little effect on temperature, as crude oil pipelines are generally equipped with heating systems.
Reply #52009-03-16
In an adiabatic condition, when the pressure decreases, the system does work on its surroundings and its temperature will drop. From the description in the question, it seems that the crude oil is depressurized using a pressure reducing valve; therefore, no phase change should occur, and it is likely that the temperature drop will not be significant.

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