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The principle behind removing stains left by silver nitrate

2009-03-02View Original

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In the titration experiment, the stains left by silver nitrate are removed using KI-I2. What is the principle behind this? What is the principle behind removing AgCl using sodium thiosulfate?
Reply #22009-03-03
Silver nitrate reacts with I- ions to form silver iodide precipitate; as for the latter reaction, it’s not clear, but it is likely that silver sulfide is formed
Reply #32009-03-03
Silver chloride is soluble in sodium thiosulfate, forming a complex of thiosulfate and silver.
Reply #42009-03-07
Silver nitrate reacts with I- ions to produce silver iodide precipitate, while silver chloride is soluble in sodium thiosulfate, forming a complex of thiosulfate and silver
Reply #52009-04-22
In sodium thiosulfate solution, it forms Ag(S2O3)2]3−

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