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I would like to ask experts: when using the lime-soda method for water softening, what pH level should be maintained? If an excessive amount of CaOH is added, doesn’t that increase the hardness again?
Lime milk reacts with carbonates in water to form insoluble CaCO3, or it reacts with alkaline substances, thereby achieving the purpose of water softening. When the alkalinity in water is greater than the hardness, the lime-gypsum softening method should be used. Because while softening the water, it is also possible to reduce its sodium salt alkalinity; the reaction is as follows: 2NaHCO3 + CaSO4 + Ca(OH)2 = 2CaCO3↓ + Na2SO4 + 2H2O. When the hardness of the water is greater than its alkalinity, the lime-soda softening method can be used – lime is employed to reduce the carbonate hardness of the water, while soda (Na2CO3) is used to reduce the non-carbonate hardness. The water quality treated by the lime softening method is unstable, as there is the following carbonate equilibrium equation in the water: Ca(HCO3)2 → CaCO3↓ + H2O + CO2. When the chemical reaction proceeds from right to left, CaCO3 dissolves, and at this point temporary hardness is re-established ; When the reaction proceeds to the right, the formation of CO2 leads to acidic corrosion, and CaCO3 may cause scaling. Lime softening is often carried out simultaneously with coagulation treatment. The coagulation process enables the CaCO3 and Mg(OH)2 formed as a result of softening to aggregate into larger particles, which then precipitate and can be removed. This not only **reduces hardness but also clarifies the water. As a coagulant, ferrous sulfate FeSO4●7H2O is generally used (since aluminum-based coagulants require a pH range of 5.5–8.5), and the pH must be kept above 8.5 in order to oxidize Fe2+ to Fe3+, thereby preventing the formation of iron scale.