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Questions regarding phase equilibrium data

2009-03-24View Original

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I am now carrying out the distillation of hydrazine hydrate and water; the bottom of the tower contains 25% hydrazine hydrate, while the top is almost pure water. After determining the gas-liquid equilibrium of hydrazine hydrate and water, I obtained the phase equilibrium data at atmospheric pressure. How can these phase equilibrium data be applied in a distillation column? 2. Also, I determined the hydrazine hydrate content using chromatography; when the concentration of hydrazine hydrate is below 15%, the chromatography method shows almost no response to the peak corresponding to hydrazine hydrate. Can I use the data from concentrations above 15% to perform regression analysis in Aspen in order to obtain values for concentrations below 15%? 3. In Aspen, there is only hydrazine, no hydrazine hydrate. Should I generate hydrazine hydrate virtually, or can I simply use mass conversion? 4. What is used within property to simulate the binary equilibrium phase diagram? Thank you!
Reply #22009-03-24
If you have the thermodynamic data for hydrazine hydrate and water, you can import it into ASPEN and then perform distillation simulations...
Reply #32009-03-24
Could you be more specific? Do you mean their interaction parameters and things like that? And is it about creating a virtual substance? Because Aspen doesn’t have hydrazine hydrate
Reply #42009-03-25
You can use Aspen Properties to fit your experimental data

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