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Why is the relative density of styrene higher than that of ethylbenzene?

2009-04-01View Original

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The molecular weight of ethylbenzene is slightly higher than that of styrene, but why is the relative density of styrene (with water = 1) greater than that of ethylbenzene? Density is usually related to molecular weight and molecular structure; can someone explain this from the perspective of molecular structure?
Reply #22009-04-02
Styrene is produced by the dehydrogenation of ethylbenzene; the atomic weight of hydrogen is 2, so styrene has a higher specific gravity than ethylbenzene.
Reply #32009-04-02
Perhaps it is because the double bonds make the molecular structure of styrene more compact
Reply #42009-04-02
Consider their spatial configuration, due to the effect of pi bonding, I guess?
Reply #52009-04-03
I’ve long forgotten the physical chemistry I learned in university; I wonder if anyone who works in theoretical research can answer this question

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