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How to prevent corrosion caused by whiskers? This topic welcomes active discussions among members, so that those who already know can review and gain new insights, while those who do not know can improve themselves, thereby achieving the goal of learning together and improving together. To facilitate scoring, it is recommended to hide the visibility of replies
This post was last edited by mopeizhi on 2010-2-7 at 12:34. The answer provided by this site is: Although humidity is not the cause of whiskers, there is still a certain relationship between humidity and whiskers. Low humidity cannot prevent the formation of whiskers, but it can significantly slow down their growth. There is a closer relationship between stress and the rate at which whiskers form: low stress can delay the emergence of whiskers. When tin is used, hot-dip plating can replace electroplating, as the hot-dip tin layer is thicker and results in lower stress ; Or melt the tin after electroplating to eliminate the stress from electroplating ; The thickest coating permitted in practice should be used as much as possible. Keeping the equipment dry and clean, and avoiding contamination by organic substances, helps to minimize the growth rate of whiskers.
This post was last edited by mopeizhi on 2010-2-7 at 12:35. I don’t know how to prevent it! This is the explanation of whiskers found on Baidu: Whiskers are fibers that grow in a single-crystal form under artificially controlled conditions; they have an extremely small diameter (on the order of micrometers), contain no defects typical of ordinary materials such as grain boundaries, dislocations, or voids, and have a highly ordered atomic arrangement, which gives them a strength close to the theoretical value of a perfect crystal. Its mechanical strength is equal to the force between adjacent atoms. The highly oriented structure of the whiskers not only endows them with high strength, high modulus, and high elongation, but also gives them electrical, optical, magnetic, dielectric, conductive, and superconducting properties. Whiskers have a strength far higher than that of other chopped fibers, and are primarily used as reinforcement agents in composite materials to produce high-strength composites. Materials used to manufacture whiskers fall into three main categories: metals, ceramics, and polymers. More than 100 materials have been found to be capable of being used to produce whiskers, mainly metals, oxides, carbides, halides, nitrides, graphite, and polymers. Whiskers can be grown from supersaturated vapor, melt, solution, or solid, and are often produced as fibers of various specifications; their forms of use include raw cotton, loose fibers, felt, or paper. Raw cotton (such as one composed of sapphire whiskers) has a very loose structure, with an aspect ratio of 500–5000∶1 and a bulk density of 0.028 g/cm3. Pine fibers have a slightly interlaced structure, with an aspect ratio of 10–200∶1. Felt-like or paper-like whiskers, arranged in a disordered manner, with an aspect ratio of 250–2500∶1. Market prospect analysis of β-SiC whiskers and their use in enhancing the properties of composite materials regarding toughness, wear resistance, corrosion resistance, and high-temperature tolerance. SiC whiskers are key new materials in high-tech fields; they serve as reinforcement agents for advanced composite materials based on metals, ceramics, and polymers, and are used in ceramic-based, metal-based, and resin-based composites. It has been widely used in ceramic cutting tools, space shuttles, automotive components, the chemical industry, machinery, and energy production. The main application area of SiC whiskers at present is the toughening of ceramic tools. The United States has successfully developed \"SiC whisker and nano-composite spraying\" for wear-resistant, corrosion-resistant, and high-temperature resistant coatings. The demand for SiC whiskers is set to increase sharply, offering very promising market prospects. Silicon carbide whiskers possess excellent mechanical properties, heat resistance, corrosion resistance, and resistance to high-temperature oxidation. This new material exhibits good compatibility with matrix materials, and in recent years it has become one of the main reinforcing and toughening agents in various high-performance composite materials. It is widely used as a composite material for metals, plastics, and ceramics. Production feasibility forecast: Silicon carbide whisker-reinforced composites can be developed for applications in aviation, **, mining and metallurgy, chemicals, the automotive industry, sports equipment, cutting tools, nozzles, and high-temperature resistant components. Silicon nitride ceramic matrix composites reinforced with whiskers possess excellent physical and mechanical properties. In addition to being used for engine components, they can also be applied in a wide range of applications requiring wear resistance, high-temperature tolerance, corrosion resistance, and impact resistance, offering broad prospects for future use. There is a large market demand for them in cutting tools, stone saws, textile cutting knives, sandblasting nozzles, high-temperature resistant extrusion dies, sealing rings, armor, and more. The structural ceramics market in North America is primarily composed of cutting tools, wear-resistant parts, components for thermal engines, and products for aviation technology. About 37% of structural ceramic components are made from ceramic matrix composites. The rest are single ceramic products. Ceramic matrix composites are primarily used in the production of cutting tools, wear-resistant parts, inserts, and products for the aerospace industry. For cutting tools, the market for products manufactured using composite ceramic matrix composites made of TiC, reinforced Si3N4 and Al2O3, as well as Al2O3 reinforced with SiC whiskers, is mostly (about 41%) composed of wear-resistant products; some types of ceramic composites are also used in radars, engines, and aircraft gas turbines. 17% of structural ceramics are used in ceramic cutting tools. These include Al2O3, Al2O3/TiC, SiC whisker-reinforced Al2O3, Si3N4, and Sialon ceramics. The rapid development of the ceramic cutting tool market is driven by the acceleration of industrialization, and the falling prices of SiC whisker-reinforced Al2O3 and Si3N4 cutting tools have also made ceramic cutting tools more competitive in the market.
This post was last edited by mopeizhi on 2010-2-7 at 12:36. As a fibrous material, whisker silicon has the following advantages when used in plastics: it improves the appearance and eliminates the visibility of glass fibers. By replacing glass fibers in various engineering plastics, it helps to prevent the exposure of those fibers, thereby enhancing the rigidity, toughness, and scratch resistance of the products. It is particularly suitable for producing precision injection-molded parts with high surface quality requirements. Reduce costs: Whisker silicon costs only about 1/2 to 1/3 of that of short glass fibers; by replacing glass fibers, it can **lower a company’s production costs. Good thermal stability and flame retardancy: Whisker silicon has a high melting point and does not decompose at high temperatures, thereby enhancing the flame retardancy and heat distortion temperature of the products. Product dimensional stability: Its excellent dispersibility enables it to disperse fully within the resin system, thereby improving the dimensional stability of the products and preventing warping. It is particularly suitable for manufacturing plastic products with high precision requirements and complex shapes. Good insulation and low water absorption: Whisker silicon has a high specific resistance and low water absorption, making it suitable for use as insulating material in cables and circuit boards. Strong corrosion resistance: Whisker silicon is primarily composed of SiO2, allowing it to remain stable in various organic solutions as well as acidic and alkaline solvents, thereby enhancing the anti-aging properties of the products. Whisker silicon is primarily used in the modification of various rubber-based products: it can be used to replace glass fibers in engineering plastics such as nylon, PP, PBT, PC, POM, and ABS. It enhances tensile strength, rigidity, scratch resistance, and flexural strength, increases modulus, reduces shrinkage, maintains dimensional stability, prevents warping, and eliminates the visibility of glass fibers ; Improve the flame retardancy, heat distortion temperature, and insulation properties of the products, **while reducing costs. Filled with PVC, PP, PE, it is used to produce profiles, pipes, and sheets, enabling the products to have good dimensional stability, as well as improved rigidity, toughness, heat resistance, and insulation properties, thus enhancing the cost-effectiveness of the products. Filled into cables and insulation sheath materials such as PVC and PE, it can enhance the product’s properties in terms of heat resistance, insulation, and acid-alkali resistance. Filling epoxy resin into copper-clad laminates can reduce the viscosity of the resin, increase its bending strength and tensile strength, improve its physical and mechanical properties, raise the glass transition temperature, lower the dielectric constant and enhance insulation performance, as well as reduce water absorption. 5. Filling with silicone resin can improve physical and mechanical properties; extensive filling can **reduce costs, making it an ideal material for manufacturing molds. Recommended addition ratios for modifying engineering plastics: Nylon + (15-20%) glass fiber + (8-12%) silicon whiskers + other additives; Nylon + 30% glass fiber + other additives. For PP, the ratio is 8% glass fiber + 10% silicon whiskers + other additives; for PP, it is 15% glass fiber + other additives. Materials such as PC, ABS, PBT, POM, PVC, and PE can also use these ratios for adding silicon whiskers. This helps to hide any exposed glass fibers, improves the appearance of the products, increases the heat deformation temperature, enhances flame resistance, reduces shrinkage and warping, prevents warping, improves processing properties, increases the rigidity of the products, and reduces costs.
This post was last edited by mopeizhi on 2010-2-7 at 12:38. Whiskers are fibers that grow in a single-crystal form under artificially controlled conditions; they have an extremely small diameter (on the order of micrometers), contain no defects typically found in materials such as grain boundaries, dislocations, and voids, and have a highly ordered atomic arrangement, which gives them a strength close to the theoretical value of a perfect crystal. Its mechanical strength is equal to the force between adjacent atoms. The highly oriented structure of the whiskers not only endows them with high strength, high modulus, and high elongation, but also gives them electrical, optical, magnetic, dielectric, conductive, and superconducting properties. Whiskers have a strength far higher than that of other chopped fibers, and are primarily used as reinforcement agents in composite materials to produce high-strength composites. Materials used to manufacture whiskers fall into three main categories: metals, ceramics, and polymers. More than 100 materials have been found to be capable of being used to produce whiskers, mainly metals, oxides, carbides, halides, nitrides, graphite, and polymers. Whiskers can be grown from supersaturated vapor, melt, solution, or solid, and are often produced as fibers of various specifications; their forms of use include raw cotton, loose fibers, felt, or paper. Raw cotton (such as one composed of sapphire whiskers) has a very loose structure, with an aspect ratio of 500–5000∶1 and a bulk density of 0.028 g/cm3. Pine fibers have a slightly interlaced structure, with an aspect ratio of 10–200∶1. Felt-like or paper-like whiskers, arranged in a disordered manner, with an aspect ratio of 250–2500∶1. Market prospect analysis of β-SiC whiskers and their use in enhancing the properties of composite materials regarding toughness, wear resistance, corrosion resistance, and high-temperature tolerance. SiC whiskers are key new materials in high-tech fields; they serve as reinforcement agents for advanced composite materials based on metals, ceramics, and polymers, and are used in ceramic-based, metal-based, and resin-based composites. It has been widely used in ceramic cutting tools, space shuttles, automotive components, the chemical industry, machinery, and energy production. The main application area of SiC whiskers at present is the toughening of ceramic tools. The United States has successfully developed \"SiC whisker and nano-composite spraying\" for wear-resistant, corrosion-resistant, and high-temperature resistant coatings. The demand for SiC whiskers is set to increase sharply, offering very promising market prospects. Silicon carbide whiskers possess excellent mechanical properties, heat resistance, corrosion resistance, and resistance to high-temperature oxidation. This new material exhibits good compatibility with matrix materials, and in recent years it has become one of the main reinforcing and toughening agents in various high-performance composite materials. It is widely used as a composite material for metals, plastics, and ceramics. Production feasibility forecast: Silicon carbide whisker-reinforced composites can be developed for applications in aviation, **, mining and metallurgy, chemicals, the automotive industry, sports equipment, cutting tools, nozzles, and high-temperature resistant components. Silicon nitride ceramic matrix composites reinforced with whiskers possess excellent physical and mechanical properties. In addition to being used for engine components, they can also be applied in a wide range of applications requiring wear resistance, high-temperature tolerance, corrosion resistance, and impact resistance, offering broad prospects for future use. There is a large market demand for them in cutting tools, stone saws, textile cutting knives, sandblasting nozzles, high-temperature resistant extrusion dies, sealing rings, armor, and more. The structural ceramics market in North America is primarily composed of cutting tools, wear-resistant parts, components for thermal engines, and products for aviation technology. About 37% of structural ceramic components are made from ceramic matrix composites. The rest are single ceramic products. Ceramic matrix composites are primarily used in the production of cutting tools, wear-resistant parts, inserts, and products for the aerospace industry. For cutting tools, the market for products manufactured using composite ceramic matrix composites made of TiC, reinforced Si3N4 and Al2O3, as well as Al2O3 reinforced with SiC whiskers, is mostly (about 41%) composed of wear-resistant products; some types of ceramic composites are also used in radars, engines, and aircraft gas turbines. 17% of structural ceramics are used in ceramic cutting tools. These include Al2O3, Al2O3/TiC, SiC whisker-reinforced Al2O3, Si3N4, and Sialon ceramics. The rapid development of the ceramic cutting tool market is driven by the acceleration of industrialization, and the falling prices of SiC whisker-reinforced Al2O3 and Si3N4 cutting tools have also made ceramic cutting tools more competitive in the market.
This post was last edited by mopeizhi on 2010-2-7 12:39 to reduce stress concentration in components.
This post was last edited by mopeizhi on 2010-2-7 at 12:44. It can’t be found; it’s difficult. Come and take a look.
Whiskers are fibers that grow in a single-crystal form under artificially controlled conditions; they have an extremely small diameter on the order of micrometers, contain no defects typically found in materials such as grain boundaries, dislocations, and vacancies, and have a highly ordered atomic arrangement, which gives them a strength close to the theoretical value of a perfect crystal. Its mechanical strength is equal to the force between adjacent atoms. The highly oriented structure of the whiskers not only endows them with high strength, high modulus, and high elongation, but also gives them electrical, optical, magnetic, dielectric, conductive, and superconducting properties. Whiskers have a strength far higher than that of other chopped fibers, and are primarily used as reinforcement agents in composite materials to produce high-strength composites. Materials used to manufacture whiskers fall into three main categories: metals, ceramics, and polymers. More than 100 materials have been found to be capable of being used to produce whiskers, mainly metals, oxides, carbides, halides, nitrides, graphite, and polymers. Whiskers can be grown from supersaturated vapor, melt, solution, or solid, and are often produced as fibers of various specifications; their forms of use include raw cotton, loose fibers, felt, or paper. Raw cotton (such as one composed of sapphire whiskers) has a very loose structure, with an aspect ratio of 500–5000∶1 and a bulk density of 0.028 g/cm3. Pine fibers have a slightly interlaced structure, with an aspect ratio of 10–200∶1. Felt-like or paper-like whiskers, arranged in a disordered manner, with an aspect ratio of 250–2500∶1. Market prospect analysis of β-SiC whiskers and their use in enhancing the properties of composite materials regarding toughness, wear resistance, corrosion resistance, and high-temperature tolerance. SiC whiskers are key new materials in high-tech fields; they serve as reinforcement agents for advanced composite materials based on metals, ceramics, and polymers, and are used in ceramic-based, metal-based, and resin-based composites. It has been widely used in ceramic cutting tools, space shuttles, automotive components, the chemical industry, machinery, and energy production. The main application area of SiC whiskers at present is the toughening of ceramic tools. The United States has successfully developed \"SiC whisker and nano-composite spraying\" for wear-resistant, corrosion-resistant, and high-temperature resistant coatings. The demand for SiC whiskers is set to increase sharply, offering very promising market prospects. Silicon carbide whiskers possess excellent mechanical properties, heat resistance, corrosion resistance, and resistance to high-temperature oxidation. This new material exhibits good compatibility with matrix materials, and in recent years it has become one of the main reinforcing and toughening agents in various high-performance composite materials. It is widely used as a composite material for metals, plastics, and ceramics. Production feasibility forecast: Silicon carbide whisker-reinforced composites can be developed for applications in aviation, **, mining and metallurgy, chemicals, the automotive industry, sports equipment, cutting tools, nozzles, and high-temperature resistant components. Silicon nitride ceramic matrix composites reinforced with whiskers possess excellent physical and mechanical properties. In addition to being used for engine components, they can also be applied in a wide range of applications requiring wear resistance, high-temperature tolerance, corrosion resistance, and impact resistance, offering broad prospects for future use. There is a large market demand for them in cutting tools, stone saws, textile cutting knives, sandblasting nozzles, high-temperature resistant extrusion dies, sealing rings, armor, and more. The structural ceramics market in North America is primarily composed of cutting tools, wear-resistant parts, components for thermal engines, and products for aviation technology. About 37% of structural ceramic components are made from ceramic matrix composites. The rest are single ceramic products. Ceramic matrix composites are primarily used in the production of cutting tools, wear-resistant parts, inserts, and products for the aerospace industry. For cutting tools, the market for products manufactured using composite ceramic matrix composites made of TiC, reinforced Si3N4 and Al2O3, as well as Al2O3 reinforced with SiC whiskers, is mostly (about 41%) composed of wear-resistant products; some types of ceramic composites are also used in radars, engines, and aircraft gas turbines. 17% of structural ceramics are used in ceramic cutting tools. These include Al2O3, Al2O3/TiC, SiC whisker-reinforced Al2O3, Si3N4, and Sialon ceramics. The rapid development of the ceramic cutting tool market is driven by the acceleration of industrialization, and the falling prices of SiC whisker-reinforced Al2O3 and Si3N4 cutting tools have also made ceramic cutting tools more competitive in the market. hide]
This post was last edited by mopeizhi on 2010-2-7 at 12:45. Whiskers are fibers that grow in a single-crystal form under artificially controlled conditions; they have an extremely small diameter on the order of micrometers, and they contain no defects typical of ordinary materials such as grain boundaries, dislocations, or vacancies. Their atomic arrangement is highly ordered, which gives them a strength close to the theoretical value of a perfect crystal. Its mechanical strength is equal to the force between adjacent atoms. The highly oriented structure of the whiskers not only endows them with high strength, high modulus, and high elongation, but also gives them electrical, optical, magnetic, dielectric, conductive, and superconducting properties. Whiskers have a strength far higher than that of other chopped fibers, and are primarily used as reinforcement agents in composite materials to produce high-strength composites. Materials used to manufacture whiskers fall into three main categories: metals, ceramics, and polymers. More than 100 materials have been found to be capable of being used to produce whiskers, mainly metals, oxides, carbides, halides, nitrides, graphite, and polymers. Whiskers can be grown from supersaturated vapor, melt, solution, or solid, and are often produced as fibers of various specifications; their forms of use include raw cotton, loose fibers, felt, or paper. Raw cotton (such as one composed of sapphire whiskers) has a very loose structure, with an aspect ratio of 500–5000∶1 and a bulk density of 0.028 g/cm3. Pine fibers have a slightly interlaced structure, with an aspect ratio of 10–200∶1. Felt-like or paper-like whiskers, arranged in a disordered manner, with an aspect ratio of 250–2500∶1. Market prospect analysis of β-SiC whiskers and their use in enhancing the properties of composite materials regarding toughness, wear resistance, corrosion resistance, and high-temperature tolerance. SiC whiskers are key new materials in high-tech fields; they serve as reinforcement agents for advanced composite materials based on metals, ceramics, and polymers, and are used in ceramic-based, metal-based, and resin-based composites. It has been widely used in ceramic cutting tools, space shuttles, automotive components, the chemical industry, machinery, and energy production. The main application area of SiC whiskers at present is the toughening of ceramic tools. The United States has successfully developed \"SiC whisker and nano-composite spraying\" for wear-resistant, corrosion-resistant, and high-temperature resistant coatings. The demand for SiC whiskers is set to increase sharply, offering very promising market prospects. Silicon carbide whiskers possess excellent mechanical properties, heat resistance, corrosion resistance, and resistance to high-temperature oxidation. This new material exhibits good compatibility with matrix materials, and in recent years it has become one of the main reinforcing and toughening agents in various high-performance composite materials. It is widely used as a composite material for metals, plastics, and ceramics. Production feasibility forecast: Silicon carbide whisker-reinforced composites can be developed for applications in aviation, **, mining and metallurgy, chemicals, the automotive industry, sports equipment, cutting tools, nozzles, and high-temperature resistant components. Silicon nitride ceramic matrix composites reinforced with whiskers possess excellent physical and mechanical properties. In addition to being used for engine components, they can also be applied in a wide range of applications requiring wear resistance, high-temperature tolerance, corrosion resistance, and impact resistance, offering broad prospects for future use. There is a large market demand for them in cutting tools, stone saws, textile cutting knives, sandblasting nozzles, high-temperature resistant extrusion dies, sealing rings, armor, and more. The structural ceramics market in North America is primarily composed of cutting tools, wear-resistant parts, components for thermal engines, and products for aviation technology. About 37% of structural ceramic components are made from ceramic matrix composites. The rest are single ceramic products. Ceramic matrix composites are primarily used in the production of cutting tools, wear-resistant parts, inserts, and products for the aerospace industry. For cutting tools, the market for products manufactured using composite ceramic matrix composites made of TiC, reinforced Si3N4 and Al2O3, as well as Al2O3 reinforced with SiC whiskers, is mostly (about 41%) composed of wear-resistant products; some types of ceramic composites are also used in radars, engines, and aircraft gas turbines. 17% of structural ceramics are used in ceramic cutting tools. These include Al2O3, Al2O3/TiC, SiC whisker-reinforced Al2O3, Si3N4, and Sialon ceramics. The rapid development of the ceramic cutting tool market is driven by the acceleration of industrialization, and the falling prices of SiC whisker-reinforced Al2O3 and Si3N4 cutting tools have also made ceramic cutting tools more competitive in the market. 1# inlegend
This post was last edited by mopeizhi on 2010-2-7 at 12:46. Whiskers are very thin single-crystal fibers with a diameter ranging from 3 to 10 μm, and a length-to-diameter ratio of 50 to 10. Since they are single-crystals, their strength is close to the values calculated theoretically. The crystal structure of these whiskers is very complete, and their cross-sections can be circular, square, or hexagonal. The shape of the cross-section is related to both the crystal structure and the growth conditions of the whiskers. Aluminum oxide whiskers, which are currently of greatest interest, have a tensile strength of 20 MPa (30 lb/in2) and an elastic modulus of 50 MPaE (620 lb/in2). Other possible whisker materials include silicon carbide, silicon nitride, boron carbide, and beryllium oxide, among others. Research and applications of whiskers have advanced in fields such as crystallography, semiconductors, and magnetism. In particular, their corrosion resistance, electrical properties, and superconducting properties have attracted increasing attention, while the fact that whiskers can maintain high strength and corrosion resistance at temperatures close to their melting point is even more noteworthy. For ordinary materials, an increase in strength is usually accompanied by an increase in brittleness; however, highly pure, high-strength, intact whiskers are strong without being brittle. These excellent properties make them suitable for use as high-temperature materials. But because whiskers are too small, they cannot be used directly as engineering materials. To use them, adhesives are employed to bind the whiskers together to form composite materials. The methods for growing whiskers include natural growth, vapor deposition, halide reduction, deposition, electrolysis, and others.
1. It contains small amounts of impurities such as silicon and iron; it has a certain degree of corrosivity in both acidic and alkaline media, but its corrosivity is lower in media containing oxidizing salts. II. If there are significant changes in humidity in the environment, oxidation will proceed abnormally, resulting in a heterogeneous oxide film that causes stress in the coating.