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Why can’t tar and ammonia water be separated?

2010-04-02View Original

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There is a layer of oil floating on top of the ammonia in the tar ship; is there any good way to solve this problem?
Reply #22010-04-02
The floating oil you are referring to is likely some high-molecular-weight aromatic hydrocarbons with very low polarity, whereas ammonia water has high polarity. So the two are insoluble. You can skim the oil off from the top, or add a surfactant to it in order to adjust the HLB value (the hydrophilic-lipophilic balance value) and enable the two to mix together. For example, Span, Tween, and the OP series are all suitable.
Reply #32010-04-04
Light oils can only be removed through overflow
Reply #42010-04-06
Don’t you have oil barriers on the upper deck of the tar ships there? An oil baffle is installed on the upper part of the tar ship; below this baffle there is an oil collection tank, through which the tar that has settled settles can be removed regularly via the side discharge port
Reply #52010-04-21
The oil on top of tar ships is generally impossible to remove; the fundamental solutions lie in the quality of the coal and the temperature of the furnace.
Reply #62010-04-21
Try using a separatory funnel; it might work
Reply #72010-04-22
The upper layer is clear tar, which can overflow through the opening of the tar vessel after a baffle plate is installed. This light oil has good dissolving capacity and can be used for spraying in cross-tube coolers. Some manufacturers sell this tar directly, as it can be used as fuel oil.
Reply #82010-04-22
Use an oil baffle to block the floating oil, and then remove it with an skimmer.
Reply #92010-04-22
Generally, there is an oil baffle above to prevent floating oil from escaping, and it is then removed using an skimmer; the key factors are the quality of your coal and the temperature in the space above the furnace.
Reply #102012-03-13
Which type of coal produces more light oil when used for coking? We are experiencing similar issues here as well

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