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Is it technically feasible to change an ion membrane cell that produces 32% alkali to one that produces 30% alkali, and will this have any impact on the ion membrane?

2010-12-11View Original

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This post was last edited by sunjl1981 on 2013-1-6 at 21:35. Our factory uses ion-exchange membrane cells for chlor-alkali production; currently we are manufacturing 32% caustic soda. I’m wondering whether it is feasible to switch to producing 30% caustic soda from a process perspective, and whether this would have any impact on the ion-exchange membranes Please give me some advice, , -
Reply #22010-12-11
Reply to 1# Weige668: For a long time, people have been striving to increase the concentration of the caustic solution in the electrolytic process for producing caustic soda – from 10% in diaphragm cells, to 20% in early ion-exchange membrane cells, to 32% at present, to 35% in the future, and above 40% in experimental settings. The goal is to save energy and reduce the costs associated with concentration. The original poster doesn’t understand why the concentration should be reduced Lowering the concentration is no problem at all; just add more water. The concentration of ion-exchange membrane caustic soda is limited by the water migration rate through the ion-exchange membrane and the properties of the carboxylate layer. Preventing hydroxide ions from migrating to the anode chamber represents the biggest technical challenge; therefore, the concentration of caustic soda cannot be increased indefinitely. Yet, increasing this concentration has always been a goal that people strive to achieve.
Reply #32010-12-11
There’s no problem with the process; just add more water. But I just can’t understand it: since everyone is now striving for high current efficiency along with high alkali concentrations, why do you still want to reduce them?
Reply #42010-12-11
Did the salesperson say that the customer will only accept 30% in physical alkali? Does the extra amount not count? We have also encountered situations where sales are not calculated on a percentage basis. It’s better when the cathode concentration is low; power consumption is then lower. .
Reply #52010-12-12
Changing the production to 30% alkali current efficiency may be affected, and the ion membrane is prone to bubbling if not controlled properly.
Reply #62010-12-12
Reply to 1# Weige668: If it is merely to meet the user’s requirements, it is recommended to install a mixer in the channel through which the liquid alkali is discharged, feed pure water into it, and use proportional control for automatic regulation. I do not recommend changing the process parameters, as this involves the DCS system and can have a significant impact; it may also affect the accuracy of the employees’ operations.
Reply #72010-12-12
The electrolyzer is not affected; it’s just that power consumption is slightly higher. More pure water needs to be used. Currently, 30% caustic soda is easier to sell in the market, and its price per 100 grams is higher, so 30% concentration is chosen for production.
Reply #82010-12-14
It is also not recommended to increase the amount of pure water added in order to reduce the alkali concentration; instead, the method suggested on the sixth floor can be adopted, which involves adding pure water to the pipes leading to the finished product tank area in order to lower the alkali concentration.
Reply #92010-12-14
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