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The relationship between vacuum degree and boiling point

2011-07-09View Original

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Surely, the higher the vacuum level, the lower the boiling point. I want to know the boiling point at normal pressure, and also what formula can be used to calculate the boiling point under a certain level of vacuum
Reply #22011-07-09
This should be found by looking it up in a table! There’s no calculation formula, right?
Reply #32011-07-09
There is no formula, and it is nonlinear. However, in general cases where the pressure is above atmospheric pressure, the Antoine equation can be used for a rough calculation; it has three parameters. The parameters are available for reference.
Reply #42011-07-09
There is no universal formula; each specific substance must be treated individually
Reply #52011-07-09
There is also a general formula for this, namely the so-called Clapeyron equation, or Clausius-Clapeyron equation. This equation is strictly valid, but it is merely a differential equation and cannot be used directly for calculation. Under certain approximate conditions, it can be integrated to yield the Antoin equation mentioned above.
Reply #62011-07-09
Normally, the vacuum level should be low, and so should the boiling point
Reply #72011-07-17
Reply to 1# No Regrets for the Past Years: There is a formula, but it was devised by an elderly professor; I can give it to you if you want it
Reply #82011-07-18
The last edit to this post was made by emirateyi on 2011-7-18 at 09:21. Another approach is to use simulation software; for example, Aspen can be used to generate bubble point curves

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