亜硫酰クロリドによるチオール置換。
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亜硫酸塩がヒドロキシ基を置き換え、二酸化硫黄と塩化水素が生成される。では、亜硫酰クロリドがチオール基を置き換えると何ができるのでしょうか？
2 -SH + 2 SOCl2 → 2-Cl + 2 HCl + SO2 + 3 S
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