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What does matrix refer to in the atomization process?

2022-04-14View Original

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During the use of a graphite furnace, the ashing step serves to remove the matrix. What exactly is meant by matrix in this context?
Reply #22022-04-15
Here, it can be understood as the substances that affect the response signal of the element being measured during analysis. It can be largely eliminated through ashing. I’m not sure if this way of phrasing is accurate. It’s better to ask the teacher to describe it.
Reply #32022-04-15
It refers to the main component of your sample; if it is an aqueous solution, then it is basically water, while if it is the residue remaining after evaporating the aqueous solution, then it is basically salts or certain oxides. The volatility and decomposability of the matrix after heating determine the amount of residue that can remain during the ashing process. Meanwhile, the thermochimical properties of the matrix may have an impact on atomization; when analyzing elements using graphite furnace atomic absorption spectroscopy, it is necessary to take into account the possible influence of the matrix on the analysis results.
Reply #42022-04-16
It’s been learned – this is a very accurate way of putting it.

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