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1. When referring to sodium hypochlorite, it is common to mention the amount of available chlorine it contains. If we are preparing sodium hypochlorite with 10% available chlorine, should the amount of chlorine gas be calculated based on the available chlorine content as the basis for such calculations? 2. Generally, 15% sodium hydroxide is used for producing hyposodium. Assuming that the amount of chlorine from the previous question is used as a basis for calculation, it is possible to determine the amount of pure sodium hydroxide required. But is 15% sodium hydroxide obtained in this way the correct concentration? For each concentration of sodium hydroxide used to prepare sodium hypochlorite, the effective chlorine content as well as the mass fraction of sodium hypochlorite remain constant. Based on the theoretical calculation for sodium hypochlorite with 10% effective chlorine, the required concentration of sodium hydroxide is around 12.5%. So, if pure sodium hydroxide is used to achieve a 15% concentration, will it be necessary to add water to the solution later on? Please give me your guidance
Sodium hypochlorite can only remain stable under strongly alkaline conditions; therefore, an excess amount of sodium hydroxide is used to maintain the strong alkalinity of the solution. If a stoichiometric amount of sodium hydroxide is used, the resulting sodium hypochlorite solution is not suitable for long-term storage and tends to decompose when heated.
Yes, the hyposodium solution must be highly alkaline. The excess alkali amount is listed in the chlor-alkali manual.
It can be calculated based on the reaction. It seems not difficult; it’s just about creating a formula using a table, but I wasn’t successful. If it’s done, I’ll upload it to you guys
If it succeeds, don’t forget about us; thank you:lol
It has a lot to do with temperature; theoretically, it’s easier to calculate using bases, while side reactions are more difficult to account for