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Process: Butane and butylene are separated from C4 through a butylene separation system; butylene is then converted into sec-butanol via hydration. Sec-butanol is heated to vaporize and fed into a dehydrogenation reactor to produce crude methylethyl ketone, which is subsequently separated into pure methylethyl ketone using a refining unit. Butanol dehydrogenation catalyst: An FDH-type dehydrogenation catalyst is used; it is an endothermic reaction, and the heat required is supplied by heat transfer oil. After being used for a certain period of time, the activity of the dehydrogenation catalyst decreases, resulting in a lower conversion rate. Raising the temperature of the heat transfer oil increases the temperature of the dehydrogenation reactor, thereby improving the conversion rate. Problem: When the temperature of the heat transfer oil is increased by 1°C, the temperature of the dehydrogenation catalyst bed remains unchanged, but the outlet temperature rises by 4°C, with the conversion rate increasing from 62% to 64%. After the equipment operates for one night, the conversion rate drops back to 62%. The current outlet temperature of the reactor is 234 degrees. Under normal operation, each increase in temperature can be maintained for about 10 days. I would like to ask what the reason for this is
It depends on the specific location of the temperature measurement points within the bed. Here, the conversion rate has changed; if there are no other factors at play, then the temperature of the bed should change as well, it’s just that the temperature measurement points do not show this change.
After running for a day and making some adjustments, it seems there is an error in the reading indicated by the outlet temperature gauge
For the butanol dehydrogenation reactor, in order to increase the conversion rate, apart from adjusting the feed amounts to each reactor and raising the temperature of the heat transfer oil in the reactors – given that the composition of the feed sample remains unchanged – are there any other effective methods? Sometimes, the conversion rate in this dehydrogenation reactor decreases after just a few days of operation
While considering improving the conversion rate, selectivity can also be taken into account to minimize temperature unevenness between the upper and lower parts of the reactor