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Why is the wastewater at the bottom of the methanol-water separation tower acidic? What is the reason for this? Some expert who knows this could please explain it to me?

2021-02-01View Original

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Why is the wastewater at the bottom of the methanol-water separation tower acidic? What is the reason for this? Is methanol an acid or a base?
Reply #22021-02-01
The bottom of the tower is almost entirely water, containing only 0.05% methanol; since methanol is neutral, this wastewater should also be neutral
Reply #32021-02-02
Are you referring to the low-temperature methanol washing process? Acidic gases dissolve in methanol, giving it an acidic nature; generally, soda ash is added at this stage to adjust the pH value.
Reply #42021-02-03
During the methanol synthesis process, formic acid is produced, which results in a certain level of acidity; therefore, an appropriate amount of alkali must be added before the material enters the distillation tower
Reply #52021-02-04
Acidic substances in the feed gas, such as HCN, dissolve in water, causing the wastewater to become acidic
Reply #62021-02-28
It is mainly the HCN in the crude syngas that causes this issue; generally, sodium hydroxide is added in the wastewater tower
Reply #72021-04-11
The water coming from the exhaust gas scrubber contains CO2, so it is acidic.

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