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Separation of diethylene glycol, triethylene glycol, tetraethylene glycol

2016-07-06View Original

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Ethylene glycol is produced by the hydration of ethylene oxide; the waste liquid resulting from the distillation and purification of ethylene glycol mainly contains diethylene glycol, triethylene glycol, tetraethylene glycol, and other substances. Does anyone know how this waste liquid is currently utilized? Is there any industrial method for separating and purifying these different types of glycols? Are there any manufacturers in China that produce products in this area? Or are there any relevant studies available?
Reply #22016-07-22
OP, if ethylene glycol is produced through hydration, then the ratio of ethylene glycol to diethylene glycol to triethylene glycol is approximately 90:9:1. Typically, there are distillation towers for ethylene glycol, as well as separate distillation towers for diethylene glycol and triethylene glycol. The output from the bottom of the triethylene glycol tower consists mainly of triethylene glycol and tetraethylene glycol, which are usually sold. Some small companies recycle these heavier alcohols; after extracting the lighter alcohols, the remaining waste has to be treated as hazardous waste. The alcohol compounds obtained in this process are usually mixtures of various alcohols, and they are primarily used by resin manufacturers with less stringent requirements. Understood?

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