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Why is hydroxylamine hydrochloride used instead of ascorbic acid in the ferroin method for measuring iron content in industrial circulating water?

2016-09-09View Original

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Why is hydroxylamine hydrochloride used instead of ascorbic acid in the o-phenanthroline method for measuring iron content in industrial circulating water? Is there any difference?
Reply #22016-09-09
There’s nothing special about it; ascorbic acid and hydroxylamine are both strong reducing agents, and their role is to reduce ferric iron to ferrous iron for measurement. It’s just that the people who developed the methods may have referred to different materials at the time; the effects of these two reducing agents are the same.
Reply #32016-09-16
We can do an experiment to see what the difference is when adding those two
Reply #42016-09-18
There shouldn’t be any difference; I remember using ascorbic acid before, and now I’m using hydroxylamine hydrochloride.
Reply #52016-09-20
Both are used as reducing agents, with hydroxylamine hydrochloride having a longer shelf life.
Reply #62016-09-28
Both are strong reducing agents, and their effects when used are essentially the same. In terms of shelf life, hydroxylamine hydrochloride is easier to store.

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