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Our company's 120,000 tons/year phosphoric acid plant adopts the dihydrate process, supporting 150,000 tons of ammonium phosphate. The phosphoric acid reaction uses a double-tank single propeller (the size of the reaction tank is: Φ 11000×6900, the effective volume of each reaction tank is: 522m3, and the motor power of the stirring paddle is 185kW). The air cooling process, the phosphoric acid filtration adopts a double-series domestic flip-plate filter, and the surface cooler cooling process. The ball mill adopts a diameter of 3.6* 6m overflow ball mill, average grinding fineness -100 mesh 70%. Due to poor cooling effect, the temperature of the extraction tank is as high as 95-100°C. In order to increase the phosphorus yield and reduce the extraction temperature, the cooling method of the extraction tank was modified in 2015. Affected by the site conditions, the 1# extraction tank adopts low-level flash cooling and the temperature is maintained at 91°C-93°C. The 2# extraction tank adopts surface cooling and the temperature is maintained at 100°C. System operation indicator liquid-to-solid ratio: 1# 2.0-2.5 ; 2# 1.8-2.2 Sulfur trioxide: 1# 0.02-0.035 ; 2# 0.02-0.025 (remarks: In order to produce 60% granular ammonium phosphate, control the extraction rate of phosphoric acid residual sulfur): 97.5%. Washing rate 99.5%, phosphoric acid concentration: 22.5-23%, the system capacity is 480 tons/day. In order to reduce the company's production costs and release the company's production capacity, it was decided to activate the original 60,000 tons of ammonium phosphate system (200 tons/day) and 100,000 tons of ammonium phosphate compound fertilizer (300 tons/day) in January 2017, which led to an increase in the production pressure of the phosphoric acid system. The average daily processing standard ore (30%) was 1,350-1,500 tons/day. The system was started on the 1.1st, and the system operation indicator liquid-to-solid ratio in the first half month: 1# 2.0-2.5 ; 2# 1.8-2.2 Sulfur trioxide: 1# 0.02-0.035 ; 2# 0.02-0.025 (remarks: In order to produce 60% granular ammonium phosphate, control the extraction rate of phosphoric acid residual sulfur): 96.5%. Washing rate 98.5%, phosphoric acid concentration: 22.5-23%, the average grinding fineness is -100 mesh 70%, and the ore blending adopts Hubei ore/Guizhou ore 2:1. Due to the serious structure of the production system in winter, after adjusting the mine, the Hubei ore/Guizhou ore 1:1, coupled with the ball mill failure, the grinding fineness is reduced to about 65%, and the system extraction rate is reduced to 90 below, the lowest is 85%, the washing rate is normal. Because the activity of Guizhou ore is suspected to be poor, the ore mix of Hubei ore/Guizhou ore is adjusted to 2:1. The extraction rate begins to rise to 95%, but it fluctuates in multiple shifts, and the fluctuation range is 90-95%. I would like to ask you for help, analyze the reasons, and please enlighten me. Attached is the pulp fineness analysis.: Grinding fineness 69.0 74.0 73.8 66.4 62.6 60.2 72.5 77.2
Analysis of the mesh number of the small ball mill on January 21: 50 mesh 95.8 60 mesh 90.4 70 mesh 86.4 80 mesh 80.8 100 mesh 69.6 120 mesh 64.0 140 mesh 60.0 160 mesh 57.0 170 mesh 51.8 250 mesh 43.8 360 mesh 36.4
The fineness of the slurry must be an important reason. Another thing I don't understand is how the temperature of the 2# tank is higher than that of the 1# tank?
The material in and out of low-level flash cooling is incorrect.
Slurry fineness is a factor that affects the extraction rate, but it is not the determining factor. Since you did not mention the acid adding method, it is recommended to check the acid adding method and acid adding point to eliminate the wrapping phenomenon.
Your phosphoric acid production capacity has great potential, and the process indicators need to be adjusted. Welcome to our unit for guidance and discussion. 13905266200