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The hydrochloric acid pickling method refers to the process of using an aqueous solution of hydrochloric acid with a concentration of 5% to 20% to remove the oxide scale and adhered salts from the surface of the workpiece. Hydrochloric acid is currently a widely used pickling raw material in hot-dip galvanizing enterprises. The lower the mass fraction of acid, the longer the pickling time required. Additionally, the temperature of pickling has a significant impact on the pickling speed. When pickling the workpieces, iron salts gradually deposit in the tank. When the iron salt concentration reaches 150–200 g/L, the tank still contains a certain amount of free acid and can be used for some time, but unless the temperature is increased, the pickling speed will **decrease**. At this point, no more new acid can be added; it must all be processed. The resin specifically designed for removing iron from hydrochloric acid exhibits excellent adsorption properties for iron-chloride complexes. It allows for large-scale treatment, is easy to regenerate, and requires simple operation. The concentrated hydrochloric acid treated with this resin has an iron ion concentration of less than 1 ppm and is colorless in appearance. This resin is mainly used for removing iron from industrial hydrochloric acid and reagent-grade hydrochloric acid. It can also be utilized for treating the hydrochloric acid produced as a by-product in paraffin chloride manufacturing plants, with the iron content after treatment meeting the requirements for industrial use.
The resin method is only suitable for small enterprises. What to do after iron ions are enriched?
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The adsorbed and saturated resin can be regenerated using pure water; the regeneration solution is an iron-containing waste acid, with an iron concentration of around 30 g/l and a hydrochloric acid content of about 16%. The neutralization precipitation method can be employed for treatment