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Methanol Purification Version – Daily Question 20200511

2020-05-11View Original

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How is a zinc-chromium catalyst reduced? Answer: Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #22020-05-11
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #32020-05-11
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #42020-05-11
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #52020-05-12
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #62020-05-12
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process; around 400°C, this transformation is completed, at which point the catalyst achieves its highest activity
Reply #72020-05-12
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #82020-05-12
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #92020-05-13
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150, mainly to remove adsorbed water ; 150-220: It reacts with the reducing agent hydrogen, causing high-valent chromium to be reduced to low-valent chromium, zinc chromate to be reduced to zinc chromite, and a large amount of water to be produced ; By 350, the reduction is essentially complete. After 350, the catalyst begins to undergo a lattice transformation process; around 400, this transformation is completed, at which point the catalyst achieves its highest activity.
Reply #102020-05-13
Methanol synthesis catalysts, whether zinc-chromium catalysts or copper-based catalysts, must be reduced before use. Before 150°C, the adsorbed water is primarily removed ; At 150°C–220°C, it reacts with the reducing agent hydrogen; high-valent chromium is reduced to low-valent chromium, zinc chromate is reduced to zinc chromite, and a large amount of water is produced ; By 350°C, the reduction is essentially complete. Above 350°C, the catalyst begins to undergo a lattice transformation process, and around 400°C this transformation is completed, at which point the catalyst achieves its highest activity.

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