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Any questions about hydrodesulfurization (catalytic dewaxing, catalytic hydrogenation)? Thiol sulfur content, catalyst loading, operational lag time

2017-06-15View Original

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The last edit to this post was made by 328104062 on 2017-6-15 at 21:51. As the title suggests: Hydrogenation unit (with dewaxing and pour point reduction functions). 1. What is the relationship between the thiol sulfur content and the supplementary refining agent (post-refining agent), and what determines the amount of this post-supplementary refining agent to be used? Why do olefins and hydrogen sulfide combine to form thiol sulfur at the bottom of the reactor? Although I know this is a reversible reaction, isn’t RSH the one that is not easiest to remove? 240 degrees is sufficient; then how can sulfur thiols be reformed at temperatures above 300°C? Where are the control steps? Hydrogen sulfide concentration? Hydrogen sulfide, as a blocker, inhibited hydrogenolysis? 2. Loading of the dewaxing (dew point reduction) catalyst: The dew point reduction catalyst contains selective molecular sieve ZSM-5; it is essentially a cracking agent that undergoes an endothermic reaction. As the temperature of the bed decreases, the reaction rate **decreases**, whereas the hydrogenation agent is exothermic. So how can hierarchical loading be used to maintain the activity of the cracking agent? Catalyst + hydrogenation agent + catalyst + hydrogenation agent? 3. Space velocity: Please check what the space velocity of the refining agents is in everyone’s diesel hydrogenation units Format: Sulfur content: 700 ppm; High-pressure value: 4.0 MPa; Space velocity of the refining agent: 4.0; Temperature: 360. Removal is very difficult, and it is hard to meet the National V standards completely. 4. What is the operating lag time for the diesel dewaxing (anti-settling) unit? For example, if the temperature of the antifreeze is increased, how long will it take to achieve a significant reduction in the freezing point – 48 hours? Manager Discussion Group
Reply #22022-10-12
Thank you for sharing; I’m eager to learn*:time::time::victory::victory:
Reply #32022-12-03
The cracking reaction continues to take place throughout the entire reactor; therefore, if no finishing agent is added to the last catalyst bed, the final cracking reaction will produce olefins, and these olefins will combine with hydrogen sulfide to form thiols. The cracking reaction involves first cracking to produce two olefins, which are then converted into alkanes through hydrogenation; therefore, the subsequent refining step is primarily aimed at saturating the olefins

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