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What should be noted during the storage and transportation of resin?

2015-11-21View Original

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What should be noted during the storage and transportation of resin?
Reply #22015-11-21
The main purpose is to prevent the loss of moisture from the resin.
Reply #32015-11-21
1. Ion exchange resins contain a certain amount of equilibrium moisture; they should be kept moist during storage and transportation to prevent dehydration. The resin should be stored indoors or under cover, with an optimal ambient temperature of 5°C to 40°C. Bagged resin should be kept away from direct sunlight, as well as from heating devices such as boilers and heaters, to prevent dehydration. If dehydration of the resin is detected, never place the resin directly in water, to prevent the dried resin from swelling rapidly upon contact with water and breaking. Depending on its degree of dehydration, about 10% saline should be slowly added to the resin, and after soaking for several hours, it should be gradually diluted with clean water. II. During long-term storage of ion exchange resins, or when they need to be stored for an extended period in equipment that is not in use, strong-type resins (strongly acidic and strongly basic resins) should be converted to their salt form, while weak-type resins (weakly acidic and weakly basic resins) can be converted to their corresponding hydrogen form or free amine form, or alternatively to their salt form, in order to maintain the stability of the resin’s properties. Then soak it in clean water. If the deactivated equipment needs to have water drained from it, it should be sealed to prevent the loss of moisture in the resin. III. For resin that has been out of use for an extended period and is stored in a exchanger, in order to prevent irreversible contamination of the resin by microorganisms such as algae and bacteria, it must be thoroughly backwashed before being put out of use, so as to remove the suspended substances that have accumulated during operation; regular flushing and water replacement are also necessary. Or, after thorough back-washing, take the following measures: For anion resins, pass a mixture of 10% NaCl + 2% NaOH in a volume three times that of the resin through the resin layer in two batches; allow it to soak for several hours each time before draining it away. If necessary, rinse the resin layer with a 0.2% hydrogen peroxide (H2O2) solution at twice the volume of resin before restarting.  Cation resin: A 0.5% formalin solution can be filled in the cation exchangers and piping systems, and this concentration should be maintained during periods of inactivity. It can also be soaked in saltwater. Rinse with a 0.2% hydrogen peroxide or 0.5% formalin solution before restarting the equipment. IV. When the ambient temperature is 0°C or below, to prevent the resin from cracking due to freezing of internal moisture, insulation measures should be taken, or the resin should be stored in saltwater of appropriate concentration depending on the temperature conditions, to avoid freezing. If it is found that the resin has frozen, it should be allowed to thaw slowly naturally; mechanical force must not be applied to the resin.
Reply #42015-11-21
It is solid or semi-solid at room temperature, generally insoluble in water, but soluble in organic solvents. Are there requirements for the transportation temperature?
Reply #52015-11-22
Ion exchange resins are widely used in the water treatment industry, and proper handling is required during transportation and storage. There are many ways to use ion exchange resins, and our website provides detailed information on this topic. If ion exchange resins are to be stored for an extended period of time, those that are strong acid or strong base types should be converted to their salt form. Resins that are weak acid or weak base types can be converted to the hydrogen form, as well as to the free amine form or the salt form. This approach helps to maintain the stability of the resins; after that, they should be immersed in clean water to prevent loss of moisture. When the temperature of the storage environment is low enough to reach the freezing point, it is necessary to take measures to prevent freezing in order to avoid cracking of the resin; this can be achieved through insulation or by storing it in saltwater, depending on the surrounding conditions, to prevent freeze damage. The optimal storage temperature for resin is between 5 and 40 degrees Celsius; it should not be exposed to direct sunlight to prevent dehydration.
Reply #62015-11-22
Precautions: 1. Ion exchange resins contain a certain amount of moisture; they should not be stored outdoors. During storage and transportation, they need to be kept moist to prevent drying out, which could cause the resin to break. If the resin dries out during storage, it should first be soaked in concentrated salt water (10%), after which the concentration can be gradually reduced. It must not be placed directly in water, as this could cause the resin to expand rapidly and break.   2. During storage and transportation in winter, it should be kept in an environment with a temperature between 5-40°C, to avoid conditions of excessive cold or heat that could affect its quality. If no insulation equipment is available in winter, the resin can be stored in saltwater, with the concentration of the saltwater depending on the temperature.   3. Industrial products of ion exchange resins often contain small amounts of low-molecular-weight polymers and monomers that have not participated in the reaction, as well as inorganic impurities such as iron, lead, and copper. When the resin comes into contact with water, acids, bases, or other solutions, these substances are released into the solution, affecting the quality of the water produced. Therefore, new resins must be pre-treated before use: first, the resin is fully expanded using water, and then the inorganic impurities (mainly iron compounds) can be removed using a 4-5% dilute acid solution, while organic impurities can be removed using a 2-4% dilute sodium hydroxide solution. The washing should continue until the solution reaches a near-neutral pH. If used in pharmaceutical preparation, it must be soaked in ethanol.   4. When in use, resins should be kept away from contact with metals such as iron and copper, oils, organic molecules, microorganisms, and strong oxidizing agents, to prevent a decrease in their ion-exchange capacity or even the loss of their functional properties. Therefore, it is necessary to carry out periodic activation treatments on the resins depending on the circumstances. The method of activation can be determined based on the level of contamination and the existing conditions. Generally, cationic resins are prone to contamination by Fe during softening processes; they can be soaked in a salt-acid solution and then gradually diluted. Anionic resins are susceptible to organic contamination and can be soaked or rinsed in a mixed solution of 10% NaCl and 2–5% NaOH; if necessary, they can also be soaked in a 1% hydrogen peroxide solution for a few minutes. Other methods include alternating acid and alkali treatments, bleaching, alcohol treatment, and various sterilization techniques.   5. Pretreatment of new resin: Industrial products of ion exchange resins often contain small amounts of oligomers and monomers that have not participated in the reaction, as well as inorganic impurities such as iron, lead, and copper. When the resin comes into contact with water, acids, bases, or other solutions, these substances dissolve into the solution, affecting the quality of the effluent. Therefore, the new resin must be pre-treated before use. Generally, the resin is first expanded with water; thereafter, inorganic impurities (mainly iron compounds) can be removed using a 4-5% dilute salt acid, while organic impurities can be removed with a 2-4% dilute sodium hydroxide solution, until the solution reaches a nearly neutral pH.

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