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Why does heat generation occur when iron oxide powder is mixed with lead soot and lead paste to form pellets?

2016-04-05View Original

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My brother works at a large company that recovers lead-acid batteries to produce recycled lead. The lead paste generated as a result of the automatic disassembly of used batteries (containing 70% Pb, 10% H2O, and 6% S) can be mixed with the lead ash produced in blast furnaces (containing 66% Pb and 7% S) to form pellets – similar to honeycomb coal pellets. When iron oxide powder (containing over 60% Fe) is added to this mixture, heat is generated. What is the principle behind this?
Reply #22016-04-06
Hello, what you added is not iron oxide powder, but fermented iron powder
Reply #32016-04-08
Lead soot contains elemental lead and lead sulfide; at low temperatures, it oxidizes to form lead oxide, lead sulfate, basic lead carbonate, etc. These reactions are exothermic.
Reply #42016-04-11
What is fermented iron powder? It can’t be found online
Reply #52016-04-11
The lead-containing material you use has a low sulfur content, so that shouldn’t be the reason. The iron powder you add is likely fermented iron powder; you can find out by asking the supplier.

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