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The pH of the wastewater from the Lindlar low-temperature methanol wash alcohol-water separation tower is low

2016-05-23View Original

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Hello everyone. Our facility uses the Linde low-temperature methanol washing process. Every time we transfer the methanol-water solution from the underground tanks to the alcohol-water separation tower, the pH of the wastewater drops to 3–4. Could someone explain why this happens?
Reply #22016-05-23
Based on what the original poster described, it is likely that the methanol aqueous solution contains some acidic substances; it is recommended to take a sample for analysis. If necessary, an alkaline solution can be added to adjust the pH. I hope my answer can help the original poster.
Reply #32016-05-24
The methanol water in the underground tank comes from the shift gas, which contains CO2 and H2S.

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