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Seeking an explanation for the azeotrope mechanism

2017-12-20View Original

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The azeotrope mechanism is not very clear. Take hydrochloric acid as an example: its azeotropic concentration is 20%, and the azeotrope temperature is 108 degrees. For example, when using 30% hydrochloric acid as the raw material and 5% hydrochloric acid as the raw material for evaporation, what should be the concentration of the product obtained through this process, and what is the mechanism behind it?
Reply #22017-12-23
This should be pretty simple, right? I believe that when 5% hydrochloric acid is heated, the vapor produced initially contains water, resulting in a very dilute acid mist with a concentration of less than 5% hydrochloric acid; as evaporation continues and the concentration inside the evaporator rises to 20%, the vapor produced thereafter consists of 20% hydrochloric acid. With 30% hydrochloric acid, what is vaporized at first is hydrochloric acid with a concentration higher than 30%; as evaporation proceeds and the concentration of hydrochloric acid in the evaporator drops to 20%, what is vaporized thereafter is all 20% hydrochloric acid. First of all, is that the case? Explain the mechanism again
Reply #32017-12-30
Should it be explained from the perspective of saturated vapor pressure?

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