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In delayed coking units, water or steam is generally used as the medium for accelerating the heating process: Disadvantages: 1. Due to the high heat capacity of water as well as its high latent heat of vaporization, more fuel is consumed; 2. Water and steam injection will eventually turn into wastewater, increasing the burden on wastewater treatment ; 3. The cooling load at the top of the distillation tower increases, resulting in higher water and electricity consumption ; 4. The water vapor partial pressure at the top of the distillation tower is high, making salt formation likely. Advantages: Low investment, easy to operate, and the technology is relatively mature. Dry gas: Used as a pressurization medium. Disadvantages: 1. 2–4 additional compressors are required to increase the pressure of the dry gas, resulting in high investment costs ; 2. Increasing the load on the compressors as well as that on the absorption and reabsorption towers leads to higher energy consumption (I’ve seen some people say that it increases the load associated with desulfurization; I don’t think that’s correct, as the dry gas cycle has little impact on the dry gas production) ; (Additionally: I’m not sure yet whether there is a corrosion issue; sulfur corrosion hardly occurs at high temperatures, but I’m not entirely certain about other types of corrosion. As for the risk of leakage, I think as long as it is properly controlled and the furnace tubes are not damaged, there shouldn’t be too many problems.) Advantages: 1. Low fuel consumption ; 2. The cooling load at the top of the distillation tower is low ; 3. Salt formation is unlikely at the top of the distillation tower ; 4. The wastewater treatment load is reduced. Modified waste hydrogen: Used as a acceleration medium. Disadvantages: 1. Increases the load on compressors as well as on absorption and reabsorption towers, leading to higher energy consumption ; 2. The impact on product quality is uncertain ; 3. The pressure is too high and difficult to control ; Advantages: 1. Low cooling load at the top of the distillation tower ; 2. The wastewater treatment load is reduced ; 3. Energy recycling ; 4. As long as the usage amount is well controlled and there is sufficient pressure, no additional equipment costs are required.
Fractionation, compressors, stability, as well as the operational load of the desulfurization system and the cooling load need to be calculated, especially during production in summer.
We have encountered coking blockages in our coking heaters; it seems that the amount of steam can be increased at critical moments, but increasing the amount of dry gas might have a significant impact on the system as well as on the heating furnace of this unit
What I am most optimistic about is using waste hydrogen produced by diesel modification of emissions; I am not optimistic about using dry gas.
With such a backstream fractionation and stabilization system, the overall gas-phase load is much higher; this issue also needs to be taken into account
The dry gas has a low pressure, low temperature, and a large temperature difference; its molecular weight is higher than that of water, which increases the load on the compressor and is not cost-effective.