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Determination of the solubility of NaOH in organic solvents in Aspen Plus

2017-01-02View Original

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Help: In Aspen Plus, regarding the dissolution of NaOH in methanol, NaOH dissociates to yield hydroxide ions; however, since water is not present, the Elec Wizard cannot be used. How should I set it up to simulate the solubility of NaOH? Seeking advice from experts :(
Reply #22017-01-03
Methanol reacts with sodium hydroxide to produce sodium methoxide and water. The entire solution system is still an electrolyte chemical equilibrium
Reply #32017-01-03
So how should it be set in the ASPEN simulation? Because there is no water, hydroxide and sodium ions cannot be added using Elec Wizard :'(
Reply #42017-01-03
First, add all the components involved in the system, including water... and then use thermodynamic methods – isn’t that enough to solve it?
Reply #52017-01-04
But the component contains no water; won’t adding water have any effect?
Reply #62017-01-04
Electrolytes are themselves aqueous solutions
Reply #72017-01-05
Mm-hmm, I understand. Thank you{:1_90:}

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