Problem of oxalate ester decomposition at high temperatures
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What is the mechanism by which dimethyl oxalate or diethyl oxalate decompose at high temperatures to produce carbonates and carbon monoxide? I personally think that metal ions may catalyze this decomposition reaction? Let’s discuss it together. No relevant literature could be found; any available materials can be shared for discussion.
What exactly is the high temperature in degrees? Are other substances produced in addition to carbonates?
It’s probably around 200 degrees, with carbon monoxide being produced at the same time