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Help needed! The Aspen distillation column results are not reasonable

2020-04-23View Original

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Hello everyone, I have just started using the Aspen simulator. Only the reactants and the target product are available in the database; the other by-products need to be added manually. There seems to be some issue with the results for the T2 distillation column – the boiling point of MDA, which is 378 degrees, is higher than that of H12MDA, which is 314 degrees. Why do both end up at the top of the column? I want to achieve 99% H12MDA at the tower top. I’ve attached the file; the process isn’t complicated and there are no loops. Please help me take a look. A beginner kneeling in gratitude; by the way, mine is version V11
Reply #22020-04-23
I forgot to mention it – my reactant is 4,4-diaminodiphenylmethane, and the target product is 4,4-diaminodicyclohexylmethane
Reply #32020-04-26
1. Is the result usable after your simulation? 2. Is a minimum boiling azeotrope formed in your system, carrying the boiling MDA to the top of the tower, resulting in a concentration that appears to be higher than that of H6MDA?
Reply #42020-04-26
Is it due to the presence of an azeotrope?
Reply #52020-04-27
This problem often occurs when using Aspen to estimate vapor pressure data for substances. Generally, NIST estimation data is used, which can lead to improvements

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