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[Q&A] April 5, 2017

2017-04-05View Original

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Question: What is the separation principle of the MTBE azeotropic distillation column? Answer: The azeotropic distillation column is used to separate MTBE from C4 and methanol, as under the given feed composition and operating conditions, C4 and MTBE form a minimum azeotrope. In this way, through the separation process in the tower, a C4 and methanol mixture is obtained at the top of the tower, while qualified MTBE product is produced at the bottom. Petrochemical deep processing version – the event to share pictures of chemical equipment has started! A vast amount of wealth, along with HaiChuan coins, is waiting for you to claim! http://bbs.hcbbs.com/thread-1760733-1-1.html 【Haixin Chemical Cup ★ Spring Has Arrived for Haichuan Chemical】Summary Post of the 2017 Scenic Views Sharing Event (You can take a look at the local scenery posted by users from various places in your free time) http://bbs.hcbbs.com/thread-1766484-1-1.html Petrochemical Zone——New Ideas for Energy Saving: The “Creative Ideas” Event (Prizes include upgraded Xiaomi phones and more) http://bbs.hcbbs.com/thread-1666758-1-1.html
Reply #22017-04-05
The azeotropic distillation column is used to separate MTBE from C and methanol, as under the given feed composition and operating conditions, C4 and MTBE form a minimum azeotrope. In this way, through the separation process in the tower, a mixture of C and methanol is obtained at the top of the tower, while qualified MTBE product is obtained at the bottom.
Reply #32017-04-05
The azeotropic distillation column is used to separate MTBE from C4 and methanol, as C4 and MTBE form a minimum azeotrope under the feed composition and operating conditions here. In this way, through the separation process in the tower, a C4 and methanol mixture is obtained at the top of the tower, while qualified MTBE product is produced at the bottom.
Reply #42017-04-05
Methanol has a higher boiling point than MTBE and is a heavier component. But it is in small quantities; it can form an azeotrope with butane, and generally, the amount of methanol in an azeotrope of 7 kilograms can reach 7.4%. Any excess of methanol beyond this amount will fall into the bottom of the tower
Reply #52017-04-05
The azeotropic distillation column is used to separate MTBE from C4 and methanol; under the feed composition and operating conditions involved, C4 and MTBE form an azeotrope. Through the separation process in this column, a mixture of C4 and methanol is obtained at the top, while a high-quality MTBE product is produced at the bottom.
Reply #62017-04-05
The azeotropic distillation column is used to separate MTBE from C4 and methanol, as C4 and MTBE form a minimum azeotrope under the feed composition and operating conditions here. In this way, through the separation action of the tower, a mixture of C and methanol is obtained at the top of the tower, while qualified MTBE product is produced at the bottom.
Reply #72017-04-05
The azeotropic distillation column is used to separate MTBE from C4 and methanol, as under the given feed composition and operating conditions, C4 and MTBE form a minimum azeotrope. Through the separation process in this column, a mixture of C4 and methanol is obtained at the top, while high-quality MTBE product is produced at the bottom.
Reply #82017-04-05
The azeotropic distillation column is used to separate MTBE from C4 and methanol, as under the given feed composition and operating conditions, C4 and MTBE form a minimum azeotrope. In this way, through the separation process in the tower, a mixture of C4 and methanol is obtained at the top of the tower, while qualified MTBE product is produced at the bottom.
Reply #92017-04-05
If two mixtures of volatile liquids are distilled, at the boiling temperature, equilibrium is established between the gas phase and the liquid phase. The vapor produced contains a higher proportion of the more volatile components; when this vapor is condensed into a liquid, its composition is identical to that of the gas phase, whereas the residue contains a higher proportion of the components with higher boiling points
Reply #102017-04-05
Azeotropic distillation is azeotropy in the lower column. Because methanol has a higher boiling point than MTBE and is a heavier component. But it is in small quantities; it can form an azeotrope with butane, and generally, the amount of methanol in an azeotrope of 7 kilograms can reach 7.4%. Any excess of methanol beyond this amount will fall into the bottom of the tower. Speaking of the upper column, it is reactive distillation. It’s not simple distillation. Each tray in the tower undergoes a reaction to produce MTBE, which then falls to the next tray. Therefore, the MTBE concentration in each layer is below the equilibrium level, which drives the reaction forward and ensures complete reaction! So virtually all of the trace amount of isobutylene reacts.
Reply #112017-04-05
Azeotropic distillation is a separation technique in which a component is added to produce a new, heterogeneous low-boiling-point azeotrope

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