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Do calcium sulfates with different amounts of crystal water have different solubilities?

2017-06-30View Original

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Does calcium sulfate with different amounts of crystal water, as mentioned in the title, have different solubilities? Thank you
Reply #22017-06-30
The solubility expressed in terms of the anhydrous form is the same, but the dissolution rates of different hydrates can differ by several orders of magnitude.
Reply #32017-06-30
Thank you. So, which one has the fastest dissolution rate: anhydrous, dihydrate, or hemihydrate? Also, for example, if a calcium sulfate solution at around 130°C is mixed with water to cool it down to around 90°C, will crystals form and cause scaling on the walls?
Reply #42017-06-30
Thank you. So, which one has the fastest dissolution rate: anhydrous, dihydrate, or hemihydrate? Also, for example, if a calcium sulfate solution at around 130°C is mixed with water to cool it down to around 90°C, will crystals form and cause scaling on the walls?
Reply #52017-06-30
Thank you. So, which one has the fastest dissolution rate: anhydrous, dihydrate, or hemihydrate? Also, for example, if a calcium sulfate solution at around 130°C is mixed with water to cool it down to around 90°C, will crystals form and cause scaling on the walls?
Reply #62017-06-30
Thank you. So, which one has the fastest dissolution rate: anhydrous, dihydrate, or hemihydrate? Also, for example, if a calcium sulfate solution at around 130°C is mixed with water to cool it down to around 90°C, will crystals form and cause scaling on the walls?
Reply #72017-06-30
Are you referring to a saturated solution of calcium sulfate or a suspension? Cooling a saturated solution from 130 degrees should not result in precipitation, as the solubility of calcium sulfate decreases as temperature rises; moreover, water has been added.
Reply #82017-06-30
Calcium sulfate with different numbers of water molecules of crystallization has varying solubilities
Reply #92017-06-30
Solubility of calcium sulfate: The solubility of CaSO4 is not high, and it shows a peculiar pattern of increasing first and then decreasing. For example, the solubility at 1°C is 0.12 g per 1 g of water (the same applies hereafter); at 4°C it is 0.2, and it drops to 0.161 at 1°C. Calcium sulfate is a white monoclinic crystal or crystalline powder. No odor. It is hygroscopic. 1 molecule of crystalline water is lost at 128°C, and all water is lost at 163°C. Soluble in acids, sodium thiosulfate, and ammonium salts; soluble in 400 parts of water; less soluble in hot water; very slowly soluble in glycerol; practically insoluble in ethanol and most organic solvents.
Reply #102017-06-30
Calcium sulfate with different numbers of water molecules of crystallization has the same solubility in water

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