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Does water in liquid ammonia freeze below zero degrees?

2017-07-05View Original

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I have a question for everyone: In ammonia refrigeration systems, the liquid ammonia contains a relatively small amount of water, around 1%, so will the water in the liquid ammonia freeze at around minus 30 degrees Celsius? The boiling point of liquid ammonia is -33.4°C, and its freezing point is -77.7°C. Liquid ammonia and water are mutually soluble.
Reply #22017-07-05
Won’t it precipitate? Saltwater freezes at temperatures lower than zero, not to mention liquid ammonia
Reply #32017-07-05
What do you mean? Will the water in liquid ammonia freeze? First of all, if the liquid ammonia is at normal pressure, the temperature must be below -33 degrees; there’s no such thing as 0 degrees in that case. Or are you asking whether the water in liquid ammonia will freeze at 0 degrees under high pressure? But the freezing point of water under high pressure is not 0 degrees, right?
Reply #42017-07-06
Ammonia water has a very low freezing point depending on its concentration; it does not freeze at 0 degrees. As far as I remember, 20% ammonia water freezes around -10 degrees. The water content in liquid ammonia is even lower; you can check the charts showing the freezing points of ammonia water
Reply #52017-07-07
This question is the same as asking whether water in saltwater freezes at zero degrees; it doesn’t freeze
Reply #62017-07-07
Ammonia water is not water; its physical and chemical properties are completely different from those of water, so it certainly will not freeze at temperatures below 0 degrees, just like water does.
Reply #72017-07-07
It won’t freeze; it’s the trace amount of water in ammonia

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