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【Frontiers in HaiChuan Chemical Technology】New progress achieved in the research on adaptive oil-gel lubricating materials at Lanzhou Institute of Chemical Physics

2025-03-03View Original

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With the rapid development of fields such as aerospace, ocean engineering, and high-end manufacturing, the negative impact of friction and wear on the performance, efficiency, and lifespan of mechanical equipment has become increasingly evident. The complex and variable harsh operating conditions pose new challenges to traditional lubricant materials. Developing high-performance adaptive lubricating materials that can change their own structure in response to external stimuli in order to adapt to complex operating conditions is of great scientific significance and practical value, as it ensures the efficient and long-lasting operation of high-end equipment. To address the issues faced by traditional lubricants in the use of new high-end equipment, such as creep, leakage, and high viscous resistance, which make it difficult to cope with complex and variable operating conditions. Recently, the Research Group on Material Surfaces and Interfaces at the National Key Laboratory of Lubricant Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, has developed a class of adaptive oleogel lubricant materials (PTA oleogels) capable of force-induced reversible phase transitions by constructing dynamic covalent networks with mechanical force-responsive properties. PTA oil gels can adapt to the start-up and shutdown of equipment, maintaining and rapidly switching between sol and gel states, and possess excellent lubrication stability as well as the ability to cope with changing operating conditions.
Reply #22025-03-03
The force-responsive properties of disulfide bonds endow PTA hydrogels with the ability to adapt to mechanical shear forces. Under the action of force, the disulfide bonds in the main chain break, resulting in partial destruction of the gel network; this causes the gel in the sheared area to transform into a low-viscosity sol state, thereby reducing viscous resistance. At the same time, the disulfide bonds are broken, resulting in the formation of sulfur radicals. Once the mechanical force is removed, these sulfur radicals can rapidly re-form bonds to rebuild the gel network, thereby enabling a phase transition from sol to gel. This process renders the lubricant non-fluid, effectively preventing problems such as slippage and leakage. Under extreme and fluctuating friction conditions, PTA oil gels exhibit excellent tribological properties and outstanding lubrication stability, further confirming their adaptability to harsh and variable operating conditions. Compared with commercial aviation greases, PTA oil gels exhibit the most balanced lubrication performance under various test conditions, as well as the best long-term lubrication characteristics.
Reply #32025-03-03
【Frontiers in HaiChuan Chemical Technology】Significant progress achieved in research on bio-based, highly efficient organic ultra-long-lasting room-temperature phosphorescence at East China University of Science and Technology https://bbs.hcbbs.com/thread-5681030-1-1.html (Source: HaiChuan Chemical Forum)
Reply #42025-03-05
【Ten Years of Rapid Development in Chemical Engineering Equipment】2228–2025: The World’s First 700 MW High-Efficiency Ultra-Supercritical Circulating Fluidized Bed Boiler https://bbs.hcbbs.com/thread-5681143-1-1.html (Source: Haichuan Chemical Engineering Forum)

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