HCBBS Forum (English)
Submit Chemical Projects / Find Solutions
Amplify Your Requirements on a Broader Chemical Platform *Engineering · Technology · Equipment · Solutions*
Submit Request

Polymerization reactor temperature adjustment

2016-03-10View Original

Thread Content

Experts: When the acetylene content in VCM is high, how should the reaction temperature in the polymerization reactor be adjusted? For example: For acetylene content of 350PPm–150PPm, by how much does the temperature of the polymerization reactor drop?
Reply #22016-03-11
For levels above 350 ppm, the temperature of the polymerization reactor drops by 0.7–1.0°C; for levels between 350 ppm and 150 ppm, the temperature drop is 0.3–0.5°C; for levels between 50 ppm and 150 ppm, the temperature drop is 0.1–0.3°C; and for levels below 50 ppm, the temperature drop is 0.1°C. This is based on personal experience and is for reference only! ! !
Reply #32016-03-14
With distillation technology being so advanced these days, there is absolutely no issue of compounds with excessively high or low boiling points! The temperature adjustment must not exceed 3°C.
Reply #42016-03-14
Based on experience and the calculation results, it is possible to reduce by 0.1 for every 20 ppm℃
Reply #52016-03-24
Hello: If the acetylene content is as high as 650–1500, will the temperature continue to drop as a result of this?
Reply #62016-03-24
This post was last edited by Forever※NeverGiveUp on 2016-3-24 at 23:06. It’s already at such a high level; why send it to polymerization? It would be better to recycle it and perform low-column distillation again. It’s at 650-1500 ppm; this could affect the type of polymer resin used. Moreover, the reaction time is long, the conversion rate is very low, and the resulting material has poor thermal stability as well as a tendency to change color. It’s better not to use it in the production process.

Submit a Project

**Looking for Chemical Technology, Equipment & Solutions?** No Registration Required Broader Platform Exposure | Global Chemical Service Provider Connections

Submit Request — Free Consultation

Disclaimer

This is an automated machine translation of the original thread. Some technical terms may have inaccuracies; the original text shall prevail. Click "View Original" at the top right to access the source page, which supports IP-based automatic real-time language translation. Please watch out for contact details and sales inducements to prevent fraud. All content and translations are for reference only, representing solely the poster's personal views. For enquiries, email service@hcbbs.com.