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Fenton reaction

2016-10-21View Original

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Gentlemen, a detailed explanation of the Fenton reaction. Proportions, concentrations, usage methods, etc.
Reply #22016-10-21
This post was last edited by zdl1966 on 2016-10-21 at 14:07. In inorganic chemical reactions, a mixture of hydrogen peroxide (H2O2) and ferrous ions (Fe) is used to oxidize many known organic compounds such as carboxylic acids, alcohols, and esters into inorganic forms. This reaction possesses a high capacity for removing refractory organic pollutants, and it is widely used in the treatment of various types of wastewater, including printing and dyeing wastewater, oily wastewater, phenol-containing wastewater, coking wastewater, ***-containing wastewater, and diphenylamine wastewater. Fe2+ + H2O2 → Fe3+ + OH- + ·OH ① H2O2 + Fe3+ → Fe2+ + O2 + 2H+ ② O2 + Fe3+ → Fe2+ + O2· ③ It can be seen that in the Fenton reagent, in addition to the formation of 1 mole of OH· radicals, 1 mole of peroxide radical O2· is also produced. However, the oxidation potential of the peroxide radical is only around 1.3 V; therefore, it is the OH· radicals that play the main role in oxidation within the Fenton reagent.
Reply #32016-10-24
It is mainly the oxidative action of hydroxyl radicals. It is a reducing substance in the oxidized water formed by ferrous ions and hydrogen peroxide at a pH value of less than 4.0; the specific dosage requires extensive pilot testing.
Reply #42016-10-26
What do you want to ask? Is it regarding the treatment of a specific type or category of water, or the basic principles? The basic principles were explained in detail on the second floor. If it’s about a particular type of water and a Fenton test is needed, it’s also necessary to know the quality of that water as well as the requirements for the treated water
Reply #52016-11-25
Based on the fundamental principles, Fenton needs to conduct more experiments in order to obtain targeted results
Reply #62016-12-07
The pH is around 3.0; I’ve conducted many experiments and find the results to be average.

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