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(Weekly Topic) Discussion on the process of converting carbon dioxide into carbon monoxide

2011-11-14View Original

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This post was last edited by GSP on 2011-11-14 at 16:58. As the title suggests, the process of producing carbon monoxide from carbon dioxide seems reasonable and economical; however, there are hardly any industrial applications for it. Let’s discuss its feasibility as well as the prospects for industrialization if it is feasible – particularly in terms of its environmental benefits Reaction equation: CO2 + C = 2CO. Personal opinion: Theoretical research on this approach is still insufficient, so the prospects for industrial application remain unclear. We welcome everyone to engage in active and in-depth discussions. Thank you!
Reply #22011-11-14
CO2+CH4=2CO+2H2: Ni-based catalyst at 630 DegC. It seems pointless to use this process for producing hydrogen through conversion, rather than for extracting CO
Reply #32011-11-14
I’m new here; does this transformation process generate a lot of carbon dioxide as well?
Reply #42011-11-14
Study it carefully*; discussions are welcome
Reply #52011-11-14
Our gas generation furnace from 20 years ago used a mixture of carbon dioxide and oxygen as the gasification agent. Now, the purified gas also has the separated carbon dioxide sent to the old gas generation furnace for gas production. It is said that a carbon tax and carbon coins will be introduced soon, which makes our system even more valuable
Reply #62011-11-14
This post was last edited by jensse on 2011-11-14 21:31. Regarding the conversion of carbon dioxide into CO, I have two ideas. The first is to use solar energy to directly decompose CO2, which requires relatively high temperatures. The second idea involves using a chemical cycle: selecting a crystal similar to a catalyst, causing it to release the oxygen from its lattice at a certain temperature, then introducing CO2 to take away the oxygen atoms from CO2 and thus form carbon monoxide, after which the crystal is restored to its original state. Of course, it's still a long way off from being truly practical
Reply #72011-11-14
This post was last edited by GSP on 2014-1-17 22:33. Carbon dioxide and carbon are heated at high temperatures to produce carbon monoxide. It is widely used in industry, especially in coking plants.
Reply #82011-11-15
This reaction should be an endothermic reaction that requires heat. Environmental benefits can only be achieved by finding a suitable catalyst.
Reply #92011-11-15
The reaction of CO2 with C has long been industrialized; the CO generation furnaces from the Saiding Coal Chemical Center have even been introduced in Taiwan
Reply #102011-11-15
That’s correct; the Coal Chemical Engineering Design Technology Center (formerly part of Caiding) holds patents for carbon monoxide generators, and it has installed one set at the Chanchang Mailiao Petrochemical plant in Taiwan.
Reply #112011-11-18
Performance details on Saiding’s official website: High-purity CO production systems. 1. Jinan Petrochemical Plant No. 2 – 20,000 tons per year of formic acid for gas production; using the company’s patented technology. Location: Jinan, Shandong. Year: 1997. 2. Zhejiang Jiangshan Chemical Co., Ltd. – 120,000 tons per year of DMF (dimethylformamide) production; using the company’s patented technology. Location: Jiangshan, Zhejiang. Year: 2002. 3. Shandong Feicheng Asde Chemical Company – 100,000 tons per year of DMF production; using the company’s patented technology. Location: Feicheng, Shandong. Year: 2003. 4. Huaihua Fine Chemicals Co., Ltd. – 100,000 tons per year of DMF production; using the company’s patented technology. Location: Huainan, Anhui. Year: 2004. 5. Inner Mongolia Yuanxing Jiangshan Chemical Co., Ltd. – CO gas supply project; 120,000 tons per year of DMF production; using the company’s patented technology. Location: Inner Mongolia. Year: 2008. 6. Taiwan Dalian Chemical Industry Co., Ltd. – CO gas supply project; 600,000 tons per year of acetic acid production; using the company’s patented technology (EP). Location: Taiwan. Year: 2008. 7. Gansu Jinchuan Group Co., Ltd. – Production lines for 10kt/a of nickel carbonyl and 5kt/a of iron carbonyl; CO gas flow rate of 5,800 Nm3/h. Using the company’s patented technology (EP). Location: Jinchang, Gansu. Year: 2009. 8. Anhui Wanwei High-tech Materials Co., Ltd. – Advanced processing project for methyl acetate; 50kt/a of acetic anhydride and 29kt/a of acetic acid; CO gas flow rate of 3,000 Nm3/h. Using the company’s patented technology (E). Location: Chaohu, Anhui. Year: 2009

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