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Under what conditions will excessive acid concentration of over 98.1 result in significant exhaust emissions?

2020-10-21View Original

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Under what conditions will excessive acid concentration of over 98.1 result in significant exhaust emissions? 94% after drying, 98.3% after the first absorption, 97.9% after the second absorption – is there little to no exhaust gas left at that point? Multiple tests of the acid concentration have shown no issues after calibration. Two-stage absorption cycle: acid temperature 85, absorption acid temperature 65, flue gas temperature 220.
Reply #22020-10-21
Two-stage SO3 absorption efficiency: 99.99%
Reply #32020-10-22
Sulfuric acid has a high degree of hygroscopicity, and inadequate precautions during testing can easily lead to moisture absorption and resulting errors. The most likely explanation for your situation is an analysis error.
Reply #42020-10-23
It is possible that the conversion reaction shifted backward, resulting in excessive acid production during the second absorption step
Reply #52020-10-26
The inlet temperature of the second absorption tower and the temperature of the acid entering the tower are both relatively high, but the difference between these two temperatures is significant: 220 – 85 = 135. Consider the following three points: 1. The amount of acid in circulation is low; check whether the current of the second absorption pump has decreased significantly; 2. Low production load, low gas volume, and low gas velocity, which affect the collision effect of the demister ; 3. A large temperature difference between gas and liquid leads to increased acid mist as a result of heat exchange
Reply #62020-10-28
Calibrate the secondary acid concentration analyzer; the acid concentration analyzer might be giving lower values
Reply #72020-10-28
Or check the exhaust pipeline of the secondary suction cycle tank

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