HCBBS Forum (English)
Submit Chemical Projects / Find Solutions
Amplify Your Requirements on a Broader Chemical Platform *Engineering · Technology · Equipment · Solutions*
Submit Request

I would like to ask if there are any good methods for removing total chlorine impurities from materials

2016-02-23View Original

Thread Content

Product: Dibenzylmethane; production process: benzene + benzoyl chloride → dibenzylmethane + HCl. After synthesis, it is washed with water to neutralize the acid and residual benzoyl chloride, then solvent removal is carried out to eliminate excess benzene, and the product is obtained through distillation. Some of the products are exported to Europe, and the customers require that the total chlorine content in the products be less than 50 ppm; however, we are currently only able to achieve a level of around 200 ppm. We have tried methods such as controlling distillation and increasing the number of tower stages, but with little success. The key issue is that we still do not know what exactly this total chlorine substance is. Even when the product’s purity reaches 99.98%, the total chlorine content remains at 200 ppm. Gas chromatography cannot detect it; it was measured using a sulfur-chlorine analyzer. I’d like to ask the experts here for any good methods to remove it
Reply #22016-02-23
Liquid caustic was used for washing; after neutralization, I tried adding sodium thiosulfate in small amounts and then conducted further tests – to my surprise, the total chlorine level remained unchanged

Submit a Project

**Looking for Chemical Technology, Equipment & Solutions?** No Registration Required Broader Platform Exposure | Global Chemical Service Provider Connections

Submit Request — Free Consultation

Disclaimer

This is an automated machine translation of the original thread. Some technical terms may have inaccuracies; the original text shall prevail. Click "View Original" at the top right to access the source page, which supports IP-based automatic real-time language translation. Please watch out for contact details and sales inducements to prevent fraud. All content and translations are for reference only, representing solely the poster's personal views. For enquiries, email service@hcbbs.com.