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Cyclopentadiene stability issue

2016-07-25View Original

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Since monomeric cyclopentadiene was needed for the experiment, I searched online and found suppliers offering high-purity cyclopentadiene reagents. Upon consulting available information, it was found that cyclopentadiene is very unstable and tends to polymerize into dimers at room temperature. Large reagent suppliers all supply dimer, while those offering cyclopentadiene monomer online are mostly unknown suppliers. It seems unreliable to buy monomers. . . . Because we don’t have a method to analyze its purity. I would appreciate some advice: can cyclopentadienyl reagent exist stably in its monomeric form, or is it possible to achieve this by adding some kind of polymerization inhibitor? Thank you!
Reply #22016-07-26
Cyclopentadiene must be stored with an inhibitor to ensure stable storage. Heating before use can distill out the monomer.
Reply #32016-07-26
Thank you, teacher. Do you mean that after adding a stabilizer to cyclopentadiene, it can remain in monomeric form, and the monomer is distilled off by heating before use to remove the stabilizer?

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