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Why does the hydrogenation catalyst HDO-18 need to be reduced?

2015-12-26View Original

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Why does the hydrogenation catalyst HDO-18 need to be reduced when it is shut down? Generally, hydrogenation catalysts lose their activity after reduction; then why does our HDO-18 catalyst (used primarily for olefin removal) need to be reduced with hydrogen in order to restore its activity?
Reply #22015-12-29
Is there any expert who knows this and can give some guidance?
Reply #32015-12-29
I’ve never heard that catalysts are reduced to increase their activity. Do they still have activity after being reduced? Waiting for experts to provide answers
Reply #42015-12-29
What is the main metal in the catalyst? Please provide information on that type of catalyst first
Reply #52015-12-31
This catalyst is used for deoxygenation of olefins; it has good reductive activity. Mainly nickel-based
Reply #62015-12-31
Why does this catalyst (HDO-18) need to be pre-sulfurized? Is its main active substance in the metallic state or the oxidized state? I would also appreciate some guidance from experts
Reply #72015-12-31
HDO-18 is a Pt catalyst on Al2O3. Oxidized state -> Reduced state -> After sulfidation, it becomes a metal sulfide.
Reply #82015-12-31
This catalyst does not require pre-sulfurization; it is a precious metal and is sensitive to sulfur
Reply #92016-01-02
Do you mean that the reactivity of the oxidized state is higher than that of the reduced state, which in turn is higher than that of the sulfided state?

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