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New breakthrough in coke oven gas hydrogenation catalysts – sulfur-free catalysts!

2016-03-16View Original

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The iron-molybdenum hydrogenation catalyst used for the deep desulfurization of coke oven gas is primarily employed to convert organic sulfur in the feed gas, with the resulting H2S being absorbed using zinc oxide or iron-manganese desulfurizing agents. However, iron-molybdenum hydrogenation catalysts require sulfidization during use, which is not very convenient; moreover, the sulfiding agents are prone to self-ignition during temporary storage. It causes safety hazards. Sulfur-free catalysts can avoid these problems; after being installed, it can be used by simply raising the temperature and introducing it into the system, just as with zinc oxide desulfurization agents. During operation with a sulfur-free catalyst, the bed temperature rises by about 100°C, and it possesses a strong deoxygenation capability, capable of removing less than 1.5% of the oxygen present. It is used for primary hydrogenation and pre-hydrogenation in Shandong and Hebei respectively. It has been in pre-hydrogenation operation for 5 months so far, and its performance in the future is under observation
Reply #22017-12-18
I use coke oven gas to produce methanol, and the high oxygen content causes the iron-molybdenum hydrogenation catalyst to overheat frequently. What kind of catalyst do you use?
Reply #32018-01-13
Which catalyst manufacturer is that? Beijing Sanju or Wuhan Collin?
Reply #42018-02-20
Looking it up online, it’s W201B, from Wuhan Collin
Reply #52020-03-13
“Xunkai Catalysts boasts a comprehensive range of hydrogenation catalyst products, including those based on Raney nickel, supported nickel, copper-zinc, copper-silicon systems, as well as catalysts on precious metal carriers – both in powder form and for fixed-bed use. These catalysts have been successfully applied in processes such as hydrogenation, dehydrogenation, reductive amination, and desulfurization across industries including those involved in 1,4-butanediol, caprolactam, fatty alcohols, organic amines, butyl octanol, HPPO, petroleum resins, dye intermediates, as well as pharmaceutical and pesticide intermediates. For technical inquiries, please contact Manager Mei at 17701646014

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