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52 Questions on 10 Years of Professional Knowledge

2016-07-06View Original

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In which of the following processes does the enthalpy remain unchanged? A. Carnot cycle of an ideal gas B. Adiabatic reversible expansion of a gas C. Condensation process of a real gas D. Throttling expansion of a real gas. I think the answers are AD, but some people say B as well. Why is that? I believe the enthalpy change is less than 0, so it should be a isentropic process. Please share your opinions
Reply #22016-07-07
A, B: There is definitely a change in enthalpy during the throttling expansion of real gases
Reply #32016-07-07
Why is there a B? In the example calculation for the adiabatic reversible compression of an ideal gas in physical chemistry, the change in enthalpy is positive, whereas it is negative during the expansion process!
Reply #42016-07-07
Reversible adiabatic expansion process: △U = W0. Does anyone see any problems with this?
Reply #52016-07-07
Yes, what you say makes sense. The reference answers provided by Kaichuan were A and B; I didn’t think much about it and assumed it should be A and D

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