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Flue gas from gypsum slag production using anhydrous hydrofluoric acid

2021-01-04View Original

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Dear teachers: The slag generated during the production of anhydrous hydrofluoric acid, namely fluoro gypsum, is often accompanied by large amounts of HF gas, resulting in a high fluoride content in the water washing and absorption tank at the end of the furnace – sometimes exceeding 20%, whereas under normal conditions this level is less than 1%. Worse situations occur during loading, as the amount of smoke is too high to allow for transportation outside. After investigating this situation for a long time, we still don’t know why it is happening I would appreciate some guidance from the teachers. Thank you.
Reply #22021-01-05
The reaction in the rotary kiln is not effective; the reaction inside the furnace is incomplete, and hydrogen fluoride is still being produced as the material moves toward the spiral at the rear of the furnace
Reply #32021-01-07
Thank you for the response. Based on the slag testing parameters, the conditions are acceptable: the calcium fluoride content in the slag is between 1.5% and 2.5%, while the sulfur content is below 1%.

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